Development of Highly Active Ir–PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases

2016 ◽  
Vol 89 (1) ◽  
pp. 113-124 ◽  
Author(s):  
Wataru Aoki ◽  
Natdanai Wattanavinin ◽  
Shuhei Kusumoto ◽  
Kyoko Nozaki
2019 ◽  
Vol 7 (23) ◽  
pp. 14019-14026 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Sungho Yoon

A novel phenanthroline-functionalized porous organic polymer (phen-POP) has been designed, and prepared for the first time without other reactive functional groups in the polymer skeleton. Post-synthetic metalation of phen-POP with IrCl3 afforded a single-site, highly active and selective catalyst for the hydrogenation of CO2 to formate.


2020 ◽  
Vol 49 (9) ◽  
pp. 2994-3000
Author(s):  
Karan Chaudhary ◽  
Manoj Trivedi ◽  
D. T. Masram ◽  
Abhinav Kumar ◽  
Girijesh Kumar ◽  
...  

Catalytic conversion of CO2via hydrogenation using in situ gaseous H2 (granulated tin metal and concentrated HCl) to produce the formate salt (HCO2−) with turnover number (TON) values of 326 to 1.065 × 105 in 12 h to 48 h of reaction at 25 °C to 80 °C has been reported.


2019 ◽  
Vol 10 (26) ◽  
pp. 6519-6523 ◽  
Author(s):  
Benjamin G. Schieweck ◽  
Niklas F. Westhues ◽  
Jürgen Klankermayer

Herein a highly active non-precious transition metal catalyst for the homogeneous hydrogenation of carbon dioxide to formate is presented. Detailed ligand optimisation enabled the development of a nickel-based catalytic system with exceptional productivity.


2017 ◽  
Vol 7 (17) ◽  
pp. 3842-3850 ◽  
Author(s):  
Sebastian D. Pike ◽  
Andrés García-Trenco ◽  
Edward R. White ◽  
Alice H. M. Leung ◽  
Jonathan Weiner ◽  
...  

This paper reports on the influences of the catalyst preparation method and ligand effects for a series of highly active Cu/ZnO colloidal catalysts for the hydrogenation of CO2 to methanol.


2014 ◽  
Vol 18 (10) ◽  
pp. 1335-1345 ◽  
Author(s):  
Xuecheng Yan ◽  
Han Guo ◽  
Dongjiang Yang ◽  
Shilun Qiu ◽  
Xiangdong Yao

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