Effects of Internal Diffusion on Liquid-Phase Hydrogenation of Styrene over Palladium Supported Alumina

1970 ◽  
Vol 73 (4) ◽  
pp. 652-656 ◽  
Author(s):  
Shoichi MATSUMOTO ◽  
Minekazu KOSHI ◽  
Toshinobu IMANAKA ◽  
Shiichiro TERANISHI

1989 ◽  
Vol 54 (11) ◽  
pp. 3003-3010 ◽  
Author(s):  
Jiří Hanika ◽  
Vladimíra Ehlová

Kinetics of the side reactions represented by the system involving hydrogenation and disproportionation of cyclohexene on a commercial catalyst CHEROX 41-00 (3%Pd/C) and on a supported palladium catalyst prepared by impregnation of aluminia with aqueous palladium dichloride (2.15% Pd/γ-Al2O3) have been investigated. As follows from the effectiveness factors of internal diffusion for individual reactions, in the region of internal diffusion, cyclohexene hydrogenation is preferred compared to disproportionation. This finding can be related to the fact that while the rate of disproportionation is controlled by cyclohexene diffusion, the rate of hydrogenation is controlled by diffusion of hydrogen.





2020 ◽  
Vol 61 (6) ◽  
pp. 869-878
Author(s):  
A. V. Rassolov ◽  
G. O. Bragina ◽  
G. N. Baeva ◽  
I. S. Mashkovsky ◽  
A. Yu. Stakheev


2017 ◽  
Vol 58 (4) ◽  
pp. 480-491 ◽  
Author(s):  
I. S. Mashkovsky ◽  
P. V. Markov ◽  
G. O. Bragina ◽  
A. V. Rassolov ◽  
G. N. Baeva ◽  
...  


2012 ◽  
Vol 86 (6) ◽  
pp. 908-912
Author(s):  
Yu. V. Minenkov ◽  
O. V. Lefedova ◽  
I. V. Smirnova ◽  
M. P. Nemtseva


2012 ◽  
Vol 33 (7-8) ◽  
pp. 1299-1305 ◽  
Author(s):  
K. Joseph Antony RAJ ◽  
M.G. PRAKASH ◽  
R. MAHALAKSHMY ◽  
T. ELANGOVAN ◽  
B. VISWANATHAN


2014 ◽  
Vol 469 ◽  
pp. 81-88 ◽  
Author(s):  
Lai Truong-Phuoc ◽  
Tri Truong-Huu ◽  
Lam Nguyen-Dinh ◽  
Walid Baaziz ◽  
Thierry Romero ◽  
...  


2005 ◽  
Vol 60 (7) ◽  
pp. 1881-1887 ◽  
Author(s):  
Prakash D. Vaidya ◽  
Vijaykumar V. Mahajani


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