Contents of Rare-Earth Elements and Heavy Metals in Soils and Snow Samples

2018 ◽  
Vol 7 (1) ◽  
pp. 27-30
Author(s):  
Станислав Винокуров ◽  
Stanislav Vinokurov ◽  
Наталия Тарасова ◽  
Natalya Tarasova ◽  
Анастасия Трунова ◽  
...  

The problem related to urban districts’ ecological and geochemical assessment due to the growth of environment’s technogenic pollution is becoming more and more important. The urban population is practically not protected from the constantly increasing exposure to toxic elements coming from solid, liquid and gaseous wastes of the city transport and manufactures located both in Moscow and in Moscow Region. Soils and snow samples on the territory of natural reserve «The Setun River’s Valley» have been analyzed with the aim of determining the contents of rare-earth elements and heavy metals by the method of inductively coupled plasma mass spectrometry. Variations in concentrations of rare-earth elements, heavy metals and indicator relationships of elements in soil samples and in snow’s solid fractions have been revealed. Has been established a chaotic distribution of rare-earth elements and heavy metals in soils, as well as a decrease of some elements’ content in snow’s solid fractions at the northeastern direction. The level of seasonal atmospheric pollution for the investigated territory has been estimated, and its possible source has been identified.

2020 ◽  
Vol 20 (3) ◽  
pp. 381-398
Author(s):  
Afieh Tatar ◽  
Masood Alipour-Asll

The Tazareh mine in the eastern Alborz coalfield is one of the most important coal-producing areas in Iran and contains medium volatile (19.1–31.5%), low sulfur (0.015–0.491%) and variable ash yield (3–31.5%) bituminous coal. In this research, a total of 21 samples were collected from the Tazareh coal layers, footwall and hanging wall. The concentrations of rare earth elements (REEs) and other elements were determined by inductively coupled-plasma mass spectrometry (ICP-MS) and inductively coupled plasma-optical emission spectrometry (ICP-OES). Additionally, traditional features of coal and host rocks were studied by X-ray diffraction (XRD) and petrographic methods. The concentration coefficient (CC) of Tazareh coal samples show that Sc (CC = 2.71), Be (CC = 2.68) and Ni (CC = 2.30) are slightly enriched, Li, Cr, Pb, Sb, V, Cs, As, Co, Cu, Nb, Y, Rb, Tl, REE, Zr, Zn, Ta and Th (0.5 < CC < 2) are normal, and concentrations of remaining trace elements are lower than the average world hard coals. The NASC-normalized REEs pattern and (La/Yb)n, (La/Sm)n, (Gd/Yb)n, and (La/Lu)n ratios in the Tazareh coal confirm that the LREEs are enriched relative to HREEs, and comparatively, the degree of LREE enrichment of coal is lower than that of coal-bearing shale and argillaceous shale. Coal-bearing strata were deposited under oxic conditions in a warm-humid climate. The average content of REE + Y in Tazareh coal (58 ppm) is lower than world coals (83 ppm), while Sc is enriched.


1995 ◽  
Vol 51 (3) ◽  
pp. 312-318 ◽  
Author(s):  
M. Barbaro ◽  
B. Passariello ◽  
S. Quaresima ◽  
A. Casciello ◽  
A. Marabini

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