Fundamental study on incineration of woody waste including seawater using the two-stage combustion method

In order to improve the thermal efficiency of the oxygen-blown IGCC (Integrated Gasification Combined Cycle) for stricter environmental standards and cost-effective option, it is necessary to adopt the hot/dry gas cleaning system. In this system, the flame temperature of medium-btu gasified fuel is higher and so NOx production from nitrogen fixation is expected to increase significantly. Also the gasified fuel contains fuel nitrogen, such as ammonia, in the case of employing the hot/dry gas cleaning system. This ammonia is easily oxidized into fuel-NOx in the combustor. For contribution to the protection of the environment and low cost operations of all kinds of oxygen-blown IGCC, low NOx combustion technology for reducing both the fuel-NOx and thermal-NOx emission has to be developed. In this paper, we clarified effectiveness of applying both the two-stage combustion and the nitrogen injection, and the useful engineering guidelines for the low-NOx combustor design of oxygen-blown gasified, medium-btu fuels. Main results obtained are as follows: (1) Based on the fundamental combustion tests using the small diffusion burner, we clarified that equivalence ratio at the primary combustion zone has to be adjusted due to the fuel conditions, such as methane concentration, CO/H2 molar ratio, and calorific values of gasified fuels in the case of the two-stage combustion method for reducing fuel-NOx emission. (2) From the combustion tests of the medium-btu fueled combustor the two-stage combustion with nitrogen direct injection into the combustor results in reduction of NOx emission to 80ppm (corrected at 16% O2) or less, the conversion rate of ammonia to NOx was 35% under the gas turbine operational conditions for IGCC in the case where fuel contains 3% of methane and 2135ppm of ammonia. By means of nitrogen direct injection, the thermal efficiency of the plant improved by approximately 0.3 percent (absolute), compared with a case where nitrogen is premixed with gasified fuel. The CO emission concentration decreased drastically, as low as 20ppm, or combustion efficiency was kept higher than 99.9%. Furthermore, based on the fundamental combustion tests’ results, the ammonia conversion rate is expected to decrease to 16% and NOx emission to 26ppm in the case of gasified fuel that contains 0.1% methane and 500ppm of ammonia. From the above results, it is clarified that two-stage combustion method with nitrogen injection is very effective for reducing both the fuel-NOx and thermal-NOx emissions at once in IGCC and it shows the bright prospects for low NOx and stable combustion technology of the medium-btu fuel.

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Study on a two-stage combustion method of woody biomass

Transactions of the JSME (in Japanese) ◽

10.1299/transjsme.2014tep0367 ◽

2014 ◽

Vol 80 (820) ◽

pp. TEP0367-TEP0367 ◽

Cited By ~ 2

Author(s):

Fumiaki ABE ◽

Masaya NAKAHARA ◽

Kenichi TOKUNAGA

Keyword(s):

Woody Biomass ◽

Combustion Method ◽

Two Stage ◽

Stage Combustion

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Gas Turbine Combustion Technology Reducing Both Fuel-NOx and Thermal-NOx Emissions for Oxygen-Blown IGCC With Hot/Dry Synthetic Gas Cleanup

Journal of Engineering for Gas Turbines and Power ◽

10.1115/1.2432896 ◽

2006 ◽

Vol 129 (2) ◽

pp. 358-369 ◽

Cited By ~ 12

Author(s):

Takeharu Hasegawa ◽

Takashi Tamaru

Keyword(s):

Direct Injection ◽

Combustion Method ◽

Nox Emissions ◽

Two Stage ◽

Stage Combustion ◽

Synthetic Gas ◽

Combustion Technology ◽

Thermal Nox ◽

Combustion Tests ◽

Fuel Nox

In order to improve the thermal efficiency of the oxygen-blown integrated gasification combined cycle (IGCC) and to meet stricter environmental restrictions among cost-effective options, a hot/dry synthetic gas cleanup is one of the most hopeful choices. The flame temperature of medium-Btu gasified fuel used in this system is high so that NOx formation by nitrogen fixation results to increase significantly. Additionally, the gasified fuel contains nitrogenous compound, as ammonia, and it produces nitrogen oxides, the fuel NOx, in the case of employing the hot/dry gas cleanup. Low NOx combustion technology to reduce both fuel-NOx and thermal-NOx emissions has been required to protect the environment and ensure low cost operations for all kinds of oxygen-blown IGCC. In this paper, we have demonstrated the effectiveness of two-stage combustion and nitrogen injection techniques, and also showed engineering guidelines for the low-NOx combustor design of oxygen-blown gasified, medium-Btu fuels. The main results obtained are as follows: (1) Based on the basic combustion tests using a small diffusion burner, we clarified that the equivalence ratio at the primary combustion zone has to be adjusted according to the fuel conditions, such as methane concentration, CO∕H2 molar ratio, and calorific values of gasified fuels in the case of the two-stage combustion method for reducing fuel-NOx emissions. (2) From the combustion tests of the medium-Btu fueled combustor, two-stage combustion with nitrogen direct injection into the combustor results in reductions of NOx emissions to 34ppm (corrected at 16% O2) or less under the gas turbine operational conditions of 25% load or higher for IGCC in the case where the gasified fuel contains 0.1% methane and 500ppm of ammonia. Through nitrogen direct injection, the thermal efficiency of the plant improved by approximately 0.3% (absolute), compared with the case where nitrogen was premixed with gasified fuel. The CO emission concentration decreased drastically, as low as 20ppm, or combustion efficiency was kept higher than 99.9%. The above results have shown that a two-stage combustion method with nitrogen direct injection is very effective for reducing both fuel-NOx and thermal-NOx emissions at once in IGCC, and it shows the bright prospects for low NOx and stable combustion technology of medium-Btu fuel.

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Fundamental Study on Ammonia Low-NOx Combustion Using Two-Stage Combustion by Parallel Air Jets

Processes ◽

10.3390/pr10010023 ◽

2021 ◽

Vol 10 (1) ◽

pp. 23

Author(s):

Kenta Kikuchi ◽

Ryuichi Murai ◽

Tsukasa Hori ◽

Fumiteru Akamatsu

Keyword(s):

Nox Reduction ◽

Axial Direction ◽

Two Stage ◽

Fundamental Study ◽

Lean Combustion ◽

Air Jets ◽

Stage Combustion ◽

Low Nox Combustion ◽

Secondary Air ◽

Air Nozzle

Ammonia, which has advantages over hydrogen in terms of storage and transportation, is increasingly expected to become a carbon-free fuel. However, the reduction of fuel NOx emitted from ammonia combustion is an unavoidable challenge. There is the report that two-stage combustion with parallel independent jets could achieve Low-NOx combustion under ammonia/methane co-firing conditions. In order to further improve NOx reduction, we experimentally evaluated the effects of secondary air nozzle parameters, such as nozzle diameter and nozzle locations, on combustion characteristics in two-stage combustion of ammonia/natural gas co-firing using parallel independent jets. As a result of the experiments under various secondary air nozzle conditions, it was found that under the conditions where NOx was significantly reduced, the peak temperature in the furnace was observed at 300–500 mm in the axial direction from the burner, and then the temperature decreased toward the downstream of the furnace. We assumed that this temperature distribution reflected the mixing conditions of the fuel and secondary air and estimated the combustion conditions in the furnace. It was confirmed that the two-stage combustion was effective in reducing NOx by forming a fuel rich region near the downstream of the burner, and the lean combustion of the unburned portion of the first stage combustion with secondary air. We confirmed that the low NOx effects could be achieved by two-stage combustion using independent jets from the same wall under appropriate combustion and air nozzle conditions.

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