scholarly journals Solid acids and their use as environmentally friendly catalysts in organic synthesis

2000 ◽  
Vol 72 (7) ◽  
pp. 1313-1319 ◽  
Author(s):  
Karen Wilson ◽  
James H. Clark

Tightening environmental legislation is driving the fine and speciality chemicals industries to consider alternative processes that avoid the use of conventional mineral acids. The use of heterogeneous catalysts in these processes would vastly simplify catalyst removal, minimizing the amount of waste formed. However, diffusion limitation of liquids within porous solids dictates that effective solid acids for liquid-phase reactions require the use of mesoporous materials <20_100Å. Recent developments in materials chemistry has led to the discovery of a family of ordered mesoporous silicas which opens up new possibilities for preparing solid-acid catalysts for liquid-phase reactions. This review concentrates on recent developments in the synthesis of new mesoporous solid acids for liquid-phase organic synthesis.

2020 ◽  
Vol 17 (6) ◽  
pp. 740-753
Author(s):  
Bishwajit Changmai ◽  
Gunindra Pathak ◽  
Jasha Momo H. Anal ◽  
Lalthazuala Rokhum

Due to its inherent advantages such as easy recovery and reuse of the catalysts/ reagents, and environmentally friendly nature, the heterogeneous system has gain popularity in the realm of organic synthesis. In recent years, several chemically or biologically potent molecules are achieved through heterogeneous synthesis strategies. By recalling some of the classical fundamentals of the heterogeneous system in important organic synthesis, this mini-review outlines the recent developments in the applications heterogeneous catalysts and reagents; particularly in the solid phase synthesis, esterification and transesterification reactions to produce biodiesel, and Henry reaction.


ChemInform ◽  
2012 ◽  
Vol 43 (12) ◽  
pp. no-no
Author(s):  
Meghshyam K. Patil ◽  
Avvari N. Prasad ◽  
Benjaram M. Reddy

2006 ◽  
Vol 78 (2) ◽  
pp. vi
Author(s):  
Alexandre Alexakis

The 13th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-13<http://omcos13.unige.ch/>) was held in Geneva, Switzerland, from 17-21 July 2005.The aim of this series of symposia is to bring together chemists from academia and industry to define and discuss the most recent developments in the areas of catalysis, new organometallic reagents and reactions, and new materials chemistry. In 2001, Sharpless, Noyori, and Knowles received the Nobel Prize for their work in this area of chemistry; and the high profile has been maintained by the award of the 2005 Nobel Prize in Chemistry to Chauvin, Grubbs, and Schrock for the development of the metathesis method in organic synthesis.OMCOS-13 had a record number of nearly 1200 participants from 41 countries, and there was an encouragingly high proportion of young scientists in attendance. Very strong Asian participation at this conference reflected the outstanding level of research and leadership in this field from countries such as Japan, China, South Korea, and Taiwan.Prof. Shengming Ma, from the Shanghai Institute of Organic Chemistry of the Chinese Academy of Science and the Department of Chemistry, Zhejiang University, China received the OMCOS-13 Award (sponsored by the Yen Chuang Foundation and Springer Verlag). The prize was awarded for his creative research contributions in the field of transition-metal-catalyzed reactions of allenes.Apart from the OMCOS-13 Award lecture, there were 23 plenary lectures and 20 oral communications that dealt with aspects of reactivity and chemoselectivity of main group and transition-metal organometallics. Stereoselectivity issues also figured prominently with a particular emphasis on asymmetric synthesis and catalysis. Mechanistic insights, new reagents for synthesis, new catalyst and ligand design, and ligand effects were other important topics.The quality of the 620 posters that were on display during the entire conference was also outstanding. This extraordinary poster session was highlighted with the Monday evening "poster party" and culminated in the awarding of 37 poster prizes.OMCOS-13 was held as a single session conference in an impressive lecture theater and a large exhibition area in the center of Geneva at a superb lakefront location. It was a fitting venue for the firstclass science that was presented.Thirty-seven lecturers of OMCOS-13 present their chemistry in this issue of Pure and Applied Chemistry and provide a fine recollection of last summer's conference. The 14th edition of OMCOS will be held in Nara, Japan (2-6 August 2007) under the chairmanship of Prof. Koichiro Oshima.Alexandre AlexakisOMCOS-13 Co-chairE. Peter KündigOMCOS-13 Co-chair


Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3270
Author(s):  
Ravi Kumar Ganta ◽  
Nagaraju Kerru ◽  
Suresh Maddila ◽  
Sreekantha B. Jonnalagadda

Heterogeneous catalysis plays a crucial role in many chemical processes, including advanced organic preparations and the design and synthesis of new organic moieties. Efficient and sustainable catalysts are vital to ecological and fiscal viability. This is why green multicomponent reaction (MCR) approaches have gained prominence. Owing to a broad range of pharmacological applications, pyranopyrazole syntheses (through the one-pot strategy, employing sustainable heterogeneous catalysts) have received immense attention. This review aimed to emphasise recent developments in synthesising nitrogen-based fused heterocyclic ring frameworks, exploring diverse recyclable catalysts. The article focused on the synthetic protocols used between 2010 and 2020 using different single, bi- and tri-metallic materials and nanocomposites as reusable catalysts. This review designated the catalysts’ efficacy and activity in product yields, reaction time, and reusability. The MCR green methodologies (in conjunction with recyclable catalyst materials) proved eco-friendly and ideal, with a broad scope that could feasibly lead to advancements in organic synthesis.


2011 ◽  
Vol 15 (23) ◽  
pp. 3961-3985 ◽  
Author(s):  
Meghshyam K. Patil ◽  
Avvari N. Prasad ◽  
Benjaram M. Reddy

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