Selective synthetic methods using vanadium-mediated redox reactions
2005 ◽
Vol 77
(9)
◽
pp. 1539-1557
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Keyword(s):
Oxovanadium(V) compounds serve as Lewis acids with oxidation capability and induce one-electron oxidative transformations of organosilicons, organotins, organoaluminums, organoborons, organozincs, and/or their ate complexes. Low-valent vanadium-catalyzed stereoselective reductive transformations, including dehalogenation, pinacol coupling, and the related radical reaction, have been developed by constructing a multicomponent redox system in combination with a coreductant and an additive.
Keyword(s):
Keyword(s):
1984 ◽
Vol 39
(11)
◽
pp. 1607-1613
◽
1986 ◽
Vol 25
(11)
◽
pp. 947-959
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