Vibrational Assignments of Organosilanetriols. II. Crystalline Phenylsilanetriol and Phenylsilanetriol-D3

1978 ◽  
Vol 32 (5) ◽  
pp. 469-479 ◽  
Author(s):  
H. Ishida ◽  
J. L. Koenig

Fourier transform infrared spectra (3800 to 450 cm−1) and laser Raman spectra (4000 to 0 cm−1) of crystalline phenylsilanetriol and phenylsilanetriol-d3, and liquid state phenylsilanetriol and phenylsilanetriol-d3 are first reported. Complete band assignments are attempted. All vibrational modes of the SiOH group except for the SiC torsional mode, including the SiOH in-plane and out-of-plane bending modes, are observed. In addition to the phenylsilanetriols, infrared and laser Raman spectra of crystalline diphenylsilanediol and triphenylsilanol are also studied to aid the band assignments.

1980 ◽  
Vol 34 (3) ◽  
pp. 327-331 ◽  
Author(s):  
Ken Ohwada

Laser Raman spectra of uranyl tetrachloride complexes [K2UO2Cl4, Rb2UO2Cl4, Cs2UO2Cl4, (NH4)2UO2Cl4] have been measured in the region from 3500 to 10 cm−1. Vibrational assignments as well as normal coordinate analyses have been carried out with the assumption that all the complexes contain discrete (UO2Cl4)2− ions belonging to a point group D4h. To understand the nature of the uranyl bonds in the complexes, approximate π-bonding energies of such bonds have been estimated from the U—O stretching force constants. The reliability of the values obtained are discussed in detail on the basis of Mulliken's magic formula.


1969 ◽  
Vol 23 (6) ◽  
pp. 610-615 ◽  
Author(s):  
Stanley K. Freeman ◽  
Dana W. Mayo

Laser-Raman spectra of 12 acyclic terpenoids has been recorded. Assignments were made for stretching mode vibrations of carbon-carbon double bonds by comparison with infrared spectra. The results of intensity and depolarization studies are discussed.


1983 ◽  
Vol 122 (1) ◽  
pp. 31-47 ◽  
Author(s):  
Mohammed Mathlouthi ◽  
Anne Marie Seuvre ◽  
Jack L. Koenig

1984 ◽  
Vol 15 (1) ◽  
pp. 29-33 ◽  
Author(s):  
Jean-Jacques Jutier ◽  
Rodrigue Savoie ◽  
Marie Pigeon-Gosselin ◽  
Paul Nadeau ◽  
Peter N. Lewis

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