Vibrational Spectra and Normal Coordinate Calculations of Chlorophosphazene Compounds. III. Polydichlorophosphazene
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Vibrational spectra and normal coordinate calculations of polydichlorophosphazene (PDP) are presented. The valence force field derived previously from the two conformers of octachlorocyclotetraphosphazene was directly transferred to a distorted “cis-plan” helical model of PDP without refinement. A reasonable agreement between the observed and calculated frequencies was obtained and the assignment of the normal modes of PDP is discussed.
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1971 ◽
Vol 49
(18)
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pp. 2931-2936
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1993 ◽
Vol 48
(1)
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pp. 44-47
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1989 ◽
Vol 44
(10)
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pp. 1214-1220
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1974 ◽
Vol 52
(14)
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pp. 2590-2602
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1992 ◽
Vol 47
(12)
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pp. 1667-1672
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1994 ◽
Vol 49
(6)
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pp. 753-758
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