Darstellung und spektroskopische Charakterisierung der Oxorhenate(V), [ReOI4]–und [ReO(SCF3)4]–/ Preparation and Spectroscopic C haracterization of the Oxorhenates(V), [ReOI4]–and [ReO(SCF3)4]–
1993 ◽
Vol 48
(1)
◽
pp. 44-47
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Keyword(s):
By ligand exchange reactions of (n-Bu4N )[ReOBr4] with NaI dissolved in acetone pure (n-Bu4N )[ReOI4], and with AgSCF3 suspended in dichloromethane (n-Bu4N )[ReO(SCF3)4] have been prepared for the first time. The vibrational spectra of both complexes are assigned according to point group C4v, supported by normal coordinate analysis based on a general valence force field. 13C and ,19F NMR spectra provide evidence for the equivalence o f the SCF3 groups.
1972 ◽
Vol 27
(8-9)
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pp. 1193-1196
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Keyword(s):
1971 ◽
Vol 49
(18)
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pp. 2931-2936
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1989 ◽
Vol 44
(10)
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pp. 1214-1220
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Keyword(s):
1992 ◽
Vol 47
(12)
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pp. 1667-1672
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Keyword(s):
1994 ◽
Vol 49
(6)
◽
pp. 753-758
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Keyword(s):