Ru(III) Catalyzed Oxidation of Ciprofloxacin by Iron(III): A Kinetic and Mechanistic Approach

2018 ◽  
Vol 30 (12) ◽  
pp. 2665-2670
Author(s):  
P.K. Asha ◽  
Vidyavati S. Shastry ◽  
V.S. Anusuya Devi
Keyword(s):  
Mechanistic Approach ◽  
Catalyzed Oxidation

Aggregation of Surfactants: Catalytic Reinforcement in Oxidation of Unsaturated E-Crotonaldehyde

2021 ◽  
Vol 58 (4) ◽  
pp. 293-302
Author(s):  
Atanu Rakshit ◽  
Suman Chowdhury ◽  
Animesh Acharjee ◽  
Kuheli Dome ◽  
Kripasindhu Karmakar ◽  
...  
Keyword(s):  
Aqueous Medium ◽  
Hexavalent Chromium ◽  
Aliphatic Aldehyde ◽  
Product Formation ◽  
Order Reaction ◽  
Spectrophotometric Measurement ◽  
Reaction Condition ◽  
Mechanistic Approach ◽  
Kinetics Of ◽  
Catalyzed Oxidation

Abstract In this work, the kinetics of the micellar catalyzed oxidation of the unsaturated aliphatic aldehyde, E-crotonaldehyde in aqueous medium under pseudo 1st-order reaction condition was spectrophotometrically investigated at 25 °C. In the spectrophotometric measurement, the rate of the reaction was recorded by the decreasing intensity of the metallic oxidant, hexavalent chromium [Cr(VI)], in acidic aliquots at 450 nm with varying concentration of surfactants and/or heteroaromatic promoters. Spectral evidences have been produced in favour of the mechanistic approach and the product formation.

A Mechanistic Studies of Mn(II) Catalyzed Oxidation of a Gabapentin by Peroxomonosulphate in Aqueous Alkaline Medium

2016 ◽  
Vol 230 (1) ◽  
Author(s):  
Abdullah M. Asiri ◽  
Aftab Aslam Parwaz Khan ◽  
Anish Khan
Keyword(s):  
Ionic Strength ◽  
Alkaline Medium ◽  
Constant Ionic Strength ◽  
Aqueous Alkaline Medium ◽  
Mechanistic Studies ◽  
Oxidative Deamination ◽  
Mechanistic Approach ◽  
Catalyzed Oxidation ◽  
Convulsant Drug

AbstractA mechanistic approach to the influence of Mn(II) catalyzed oxidative deamination of an anti-convulsant drug [GP] by peroxomonosulphate (PMS) at a constant ionic strength of 1.0 mol dm

Osmium(VIII) catalyzed oxidation of an antibiotic drug chloramphenicol by hexacyanoferrate(III) in aqueous alkaline medium: A mechanistic approach

2013 ◽  
Vol 12 (1) ◽  
pp. 1-14
Author(s):  
Mahantesh B. Budri ◽  
Zahiruddin A. Mangalgatti ◽  
Megharaj B. Hullur ◽  
Manjunath D. Meti ◽  
Sharanappa T. Nandibewoor ◽  
...  
Keyword(s):  
Alkaline Medium ◽  
Aqueous Alkaline Medium ◽  
Mechanistic Approach ◽  
Antibiotic Drug ◽  
Catalyzed Oxidation
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