Failure analysis showing the effect of sulphur content in stainless steel on the resistance to stress corrosion cracking in marine environments at ambient temperatures

2014 ◽  
Vol 2 (2) ◽  
pp. 87
Author(s):  
Paul Roffey
CORROSION ◽  
1982 ◽  
Vol 38 (6) ◽  
pp. 347-353 ◽  
Author(s):  
S. Ahmad ◽  
M. L. Mehta ◽  
S. K. Saraf ◽  
I. P. Saraswat

Abstract Stress corrosion cracking (SCC) investigations of sensitized 304 austenitic stainless steel were conducted using U-bend specimens of 6.45 and 12.85 mm radii of curvature in Samans solution, which represents the polythionic acid solution formed in the petroleum refineries during shutdown as a result of the interaction of the sulfide scale on the steel surface with moisture and oxygen at ambient temperatures. The chemical analysis of the Samans solution revealed that it contained seven different constituents varying in concentration. They are sulfuric, sulfurous, and thionic acids (di-, tri-, tetra-, penta-, and hexathionic acid). The role of each individual constituent of Samans solution on SCC has been studied. The results of the chemical analysis of the test solutions after failure revealed that out of all constituents of the Samans solution, only tetrathionic acid induced stress corrosion failure of sensitized 304 austenitic stainless steel. The metallographic studies of the fractured surfaces conducted by SEM revealed intercrystalline mode of fracture in all the cases in which the samples cracked.


2012 ◽  
Vol 591-593 ◽  
pp. 1094-1097
Author(s):  
De Qiang Wei ◽  
Xin Dong ◽  
Shan Qiu Li

As a kind of corrosion resistant material, stainless steel is widely used in petroleum, chemical, pharmaceutical. Stress corrosion cracking is a main reason that why the stainless steel became disabled. Therefore, it is very necessary to research and study the stress corrosion cracking of stainless steel .The failure analysis to the sample is conducted aiming at the stress corrosion of the stainless steel piston cylinder in a factory. The analysis includes macro analysis, metallographic observation, scanning electron microscopy analysis and XRD analysis. The results of the study show that it is nonmetallic inclusion on the grain boundary, the chloridion in the industrial circulating water and the rough columnar austenitic grains in the organization of the samples that lead to the stress corrosion cracking of the piston cylinder.


2010 ◽  
Vol 89-91 ◽  
pp. 709-714 ◽  
Author(s):  
Fuad Mohamed Khoshnaw ◽  
Hussein Bakir Rahmatalla

This study investigated stress corrosion cracking of two welded stainless steel alloys, austenitic 304L and duplex 2205, in an acidic chloride solution. Different heat inputs are selected for welding the alloys, using tungsten inert gas, with and without filler metal. The slow strain rate technique is utilized to estimate the susceptibility of each weldment to stress corrosion cracking. Different strain rates are used, and the experiments showed that the strain rate equal to 1.66x10-6/sec is a critical value that can be used for assessing the susceptibility of the alloys to corrosion cracking. A numerical index used in this study to evaluate this susceptibility, which is based on a ratio between elongation percent of each alloy in the solution to that in the air. The results showed that the austenitic alloy has higher ductility than duplex in air, while there was not a big difference between both alloys in the solution. Increasing the heat input in autogenous welding caused a brittleness, i.e. less elongation, for both alloys. The results showed that the austenitic alloy is exposed to stress corrosion cracking in the solution, before and after welding, with or without filler metals. On the other hand, the duplex alloy showed higher resistance to stress corrosion cracking than the austenitic alloy due to the high chromium content, and it is dual phase.


CORROSION ◽  
1981 ◽  
Vol 37 (7) ◽  
pp. 412-415 ◽  
Author(s):  
S. Ahmad ◽  
M. L. Mehta ◽  
S. K. Saraf ◽  
I. P. Saraswat

Abstract Stress corrosion cracking investigations on U-bend samples of sensitized 304 austenitic stainless steel have been conducted in sulfurous acid solutions in the concentration range, 0.40 to 10% at ambient temperatures. Samples were found to fracture in solutions of more than 3% sulfurous acid. Chemical analysis of solutions after tests showed appreciable reduction in concentration of H2SO3, formation of H2SO4, and also the presence of Fe, Cr, and S ions. Some model experiments were carried out to ascertain the chemical species causing stress corrosion cracking and the role of oxygen and FeS in generating them. Bubbling of oxygen gas through (1) solution of H2SO3 with sample, (2) distilled water with FeS chips, and (3) solution of H2SO3 with FeS chips and sample, resulted in the formation of tetrathionic acid. Results indicate that the sulfurous acid does not directly cause cracking but it is the tetrathionic acid formed by either the interaction of sulfurous acid and austenitic stainless steel or the interaction of FeS and oxygen, that is responsible for cracking. Metallorgraphic examinations of the fracture confirmed intergranular cracking.


Alloy Digest ◽  
2010 ◽  
Vol 59 (8) ◽  

Abstract NAS 64 is a duplex stainless steel with molybdenum for pitting and crevice corrosion resistance and a duplex microstructure for resistance to stress-corrosion cracking. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-1072. Producer or source: Nippon Yakin Kogyo Company Ltd.


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