Synthesis of novel push-pull fluorescent dyes – 7-(diethylamino)furo[3,2-c]coumarin and 7-(diethylamino)thieno[3,2-c]coumarin derivatives

2018 ◽  
Vol 24 (2) ◽  
pp. 85-91 ◽  
Author(s):  
Igor O. Akchurin ◽  
Anna I. Yakhutina ◽  
Andrei Y. Bochkov ◽  
Natalya P. Solovjova ◽  
Valerii F. Traven

AbstractNovel push-pull fluorescent dyes, 7-(diethylamino)furo[3,2-c]coumarin and 7-(diethylamino)thieno[3,2-c]coumarin derivatives, were designed and synthesized using formyl derivatives of furo- and thieno[3,2-c]coumarins as key intermediates. Electron absorption and emission spectra of the dyes were recorded in different solvents. The longest-wave bands in the electron absorption spectra of the dyes are suggested to be of push-pull nature.

1993 ◽  
Vol 84 (5) ◽  
pp. 899-902 ◽  
Author(s):  
J. Hanuza ◽  
L. Macalik ◽  
B. Macalik ◽  
W. Stręk

2008 ◽  
Vol 55 ◽  
pp. 36-41 ◽  
Author(s):  
Volker Schmitt ◽  
Stefan Glang ◽  
Jasmin Preis ◽  
Heiner Detert

Fluorescent dyes with a high sensitivity of their optical spectra towards changes of the environment were prepared via aldol condensation or Horner olefinations. The main chromophore is a quadrupolar N-substituted 1,4-distyrylbenzene which allows protonation and complexation at various positions resulting in a series of different and significant changes of the optical spectra. The sensitivity of the absorption and emission spectra on solvent polarity, acid, and cations is reported.


Author(s):  
V. A. Kuznetsov ◽  
A. N. Egorochkin ◽  
N. S. Vyazankin ◽  
N. A. Pritula ◽  
M. G. Gevenyan

2019 ◽  
Vol 21 (18) ◽  
pp. 9246-9254 ◽  
Author(s):  
G. V. Baryshnikov ◽  
R. R. Valiev ◽  
V. N. Cherepanov ◽  
N. N. Karaush-Karmazin ◽  
V. A. Minaeva ◽  
...  

The electronic structure, absorption and emission spectra, aromaticity and photophysical behavior of the recently synthesized tetrasilatetrathia[8]circulene and tetragermatetrathia[8]circulene compounds have been studied computationally.


1995 ◽  
Vol 135 (1-4) ◽  
pp. 15-18 ◽  
Author(s):  
E. Martins ◽  
S. L. Baldochi ◽  
S. P. Morato ◽  
N. D. Vieira ◽  
A. Luci ◽  
...  

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