Acidic oxidation of kraft lignin into aromatic monomers catalyzed by transition metal salts
Abstract As one of the three main components in woody biomass, lignin is an abundant but underused renewable raw material and carbon source. Owing to its aromatic structure and large availability as a by-product of pulping, its conversion into chemicals is highly attractive. In the present work, the oxidation of a softwood kraft lignin in acidic media was investigated in the presence of a homogeneous catalyst. The objective was to find a cheap but efficient catalyst for the depolymerization of kraft lignin into aromatic monomers. Different transition metal salts were screened and compared to phosphomolybdic acid, which was investigated in previous studies, and to experiments in sulfuric acid without additional catalyst. Vanillin and methyl vanillate were the main monomeric products detected by gas chromatography/mass spectrometry but their formation was only slightly increased by using transition metal salts (up to 6.28 wt% yield). However, the presence of iron or copper chloride resulted in fast formation kinetics and significant amounts of other monomeric products. In addition, an efficient fragmentation of the lignin molecule from a weight-average molecular weight of 3500 g mol-1 down to 500 g mol-1 was observed by size-exclusion chromatography. The enhanced incorporation of oxygen into the reaction products in the presence of those catalysts was proven by Fourier transform infrared spectroscopy and the influence of the catalyst concentration was studied.
