Liquid Phase Epoxidation of Allylic Compounds with Hydrogen Peroxide at Autogenic and Atmospheric Pressure over Mesoporous Ti- MCM-48 Catalyst
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AbstractThe epoxidation of allylic compounds: allyl alcohol, methallyl alcohol and methallyl chloride to corresponding epoxides: glycidol, 2-methylglycidol and 2-methylepichlorohydrin with hydrogen peroxide over Ti-MCM-48 catalyst has been studied. The epoxidation was carried out with 30 wt% hydrogen peroxide in methanol as a solvent under autogenic pressure (in autoclave) and at atmospheric pressure in a glass reactor. The optimal technological parameters and regions of advantageous changes of: temperature, the molar ratio allylic compound/H
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2014 ◽
Vol 63
(12)
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pp. 2647-2651
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2015 ◽
Vol 17
(4)
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pp. 23-31
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2012 ◽
Vol 10
(1)
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2005 ◽
Vol 229
(1-2)
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pp. 207-210
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