Techno-Economical Evaluation of Bio-Oil Production via Biomass Fast Pyrolysis Process: A Review

Biomass pyrolysis is one of the beneficial sources of the production of sustainable bio-oil. Currently, marketable bio-oil plants are scarce because of the complex operations and lower profits. Therefore, it is necessary to comprehend the relationship between technological parameters and economic practicality. This review outlines the technical and economical routine to produce bio-oils from various biomass by fast pyrolysis. Explicit pointers were compared, such as production cost, capacity, and biomass type for bio-oil production. The bio-oil production cost is crucial for evaluating the market compatibility with other biofuels available. Different pretreatments, upgrades and recycling processes influenced production costs. Using an energy integration strategy, it is possible to produce bio-oil from biomass pyrolysis. The findings of this study might lead to bio-oil industry-related research aimed at commercializing the product.

Electroplating of Indium-Cadmium and Tin-Cadmium Alloy Coatings

Technological parameters for electroplating cadmium alloy (Cd (24)-In and Cd (33)-Sn) coatings from low toxic solutions have been proposed. Since the fabricated alloy coatings possess low internal stress and microhardness, good adhesion property, high corrosion and wear resistance, they can be used as protective coatings for machine building products to enhance reliability and operability thereof. The presence of good solderability and low values of transient electric resistance in climatic testing favor these coatings to be applied in hetero-structured contact systems of instrument making products for increasing their reliability and operability in a tropical marine climate.

Controlling the Stress State of the Coating during Plasma Spraying

Coatings obtained by spraying materials with a high-temperature gas jet onto a substrate followed by thermal treatment of the deposited materials (thermal gas coatings) are increasingly being used. The practical experience of using thermal spray coatings, accumulated over the past 20–30 years in industries, shows that in this way it is possible, as a rule, to reduce the wear of machine parts operating under various conditions by a factor of 2–5. The effectiveness of the technology has also been proven in the protection of products from corrosion and thermal damage. The efficiency of the applied materials is determined by their structure, which largely depends on the choice of the composition of the material, the method, and modes of application. A comprehensive solution to these issues with the study of the mechanism of the processes of formation of thermal gas coatings will create a scientific basis for the technology for its successful implementation in production. At the same time, the importance of studying the processes and optimizing the technological parameters of spraying and subsequent coating treatment increases. Optimization is carried out, as a rule, according to the results of experiments. Let us consider the study on the example of the development of wear-resistant composite coatings with solid lubricant inclusions with the substantiation of the technique and criteria for optimizing technological parameters taking into account the most important properties of sprayed protective coatings.

Smelting options for carbon ferrochrome based on ore raw materials, middlings and their technological evaluation

The article presents the results of large-scale laboratory tests carried out in the conditions of the Chemical and Metallurgical Institute named after V.I. Zh. Abishev on the use of briquetted mono-charge in the smelting of carbon ferrochrome on a 250 kVA furnace. The purpose of these studies was to determine the technological parameters of the use of briquetted mono-charge containing in its composition chrome ore, wastes from the production of high-carbon ferrochrome, middlings and various carbonaceous reducing agents. The main idea of using these briquettes was to multiply the contact surface of the reductant and ore, which should speed up the technological process. The principal possibility of smelting a standard alloy using briquetted mono-charge is shown. The alloy for individual charge options meets the requirements of the standards. In comparison with the technology without the use of briquettes, the mono-charge technology has shown advantages in all main parameters. The technology with the use of briquettes from the dust of the AktZF gas cleaning system is distinguished by a low yield of non-standard metal and slag, the bulk of the material goes into the gas collection system. Technologies from briquettes from fines pellet production area of Donskoy ore mining and processing plant and flash have very low specific technical and economic indicators and cannot be recommended for industrial use. Improvement of briquetting modes and technology of their smelting is required. The technical and economic indicators were higher than the current one, showed briquettes from ore and coke of the People's Republic of China, briquettes of ore from borlin and shubarkol coals of Kazakhstan.

Load capacity of single-lap adhesive joints made of 2024-T3 aluminium alloy sheets after shot peening

The goal of the work reported was to determine the influence of selected shot peening parameters on the deflection of the Almen strip and the load capacity of single-lap adhesive joints made of 2-mm-thick aluminium alloy EN AW-2024-T3. Moreover, the research was aimed at checking the possibility of using the Almen strip deflection indicator to predict the load capacity of adhesive joints after shot peening. The analysis was carried out according to Hartley’s PS/DS-P:Ha3 plan. The input factors were the shot peening parameters: treatment time t (60–180 s), ball diameter dk (0.5–1.5 mm) and compressed air pressure p (0.3–0.5 MPa). It has been proved in this work that shot peening treatment of the outer surface of single-lap adhesive joints can be used to strengthen the joint. The maximum increase in the load capacity of the shot peened joints was 33.4%. It was observed that the load capacity of the joints decreases with an increase in the deflection of the Almen strip (in the assumed area of variability of technological parameters). Moreover, the results obtained indicate that the adoption of too intensive treatment, manifested in high values of deflection of the Almen strip, may weaken single-lap adhesive joints.

Ultra-Narrow Gap Fiber Laser Conduction Welding Technology for 304 Stainless Steel Thick Plates and the Mechanical Properties of Welding Joints

The application of thick metal plates is increasing, and the welding problem is becoming more and more prominent. Narrow gap laser welding is one of the important methods, and it is also a research hotspot. The stainless steel thick plates were welded using the ultra-narrow gap fiber laser conduction welding with filler wire. Results show that the ranges of technological parameters for the achievement of the weld seam with no defects are smaller when the gap width is comparatively larger. Using the optimized technological parameters, the butt welding with no defects on the 3 mm gap between two 304 stainless steel plates with 60 mm thickness was achieved through the filling 20 times. This welding method of 304 metal with large thickness is rare in the literature. The tensile strength of the welding joint can be up to 87% of that of the base metal, and the micro-hardness and yield strength of the joint are comparable with those of the base metal.

АЛГОРИТМ ПРОЕКТУВАННЯ АВТОМАТИЗОВАНИХ ЗМІШУВАЛЬНИХ КОМПЛЕКСІВ БЕЗПЕРЕРВНОЇ ДІЇ ДЛЯ СИПКИХ МАТЕРІАЛІВ

Purpose. Creation of design algorithm of continuous action mixing complexes that will allow defining parameters of the equipment proceeding from requirements to quality, productivity and the set compounding of mixture.Methodology. The method of discrete elements, classical mechanics positions, theory of solids contact interaction, method of mathematical modeling are used in the work.Findings. The paper proposes a generalized algorithm for designing a continuous mixing complex for bulk materials. The procedure for designing a centrifugal mixer, the flow shapers, plate feeders and conical-cylindrical hoppers are presented. Calculations of design and technological parameters are carried out on the basis of information about the physical and mechanical properties of bulk components particles, requirements for equipment performance and the mixture homogeneity. The results of calculations of the mixing complex for the three-component mixture used for the production of polyethylene film are presented. To test the proposed algorithm, a mathematical model based on the discrete elements method is created. The mixing process is modeled and the coefficients of inhomogeneity of each of the components in the finished mixture are determined. The obtained results confirmed that the proposed algorithm allows to determine the parameters of the mixing complex, which ensure compliance with the specified requirements for the quality and the equipment performance.Originality. Mathematical models of bulk motion dynamics in mixing complexes are improved, which include bunker devices, plate feeders, flow shapers and continuous centrifugal mixer, taking into account the bulk motion discrete nature.Practical value. The obtained results allow calculating the design and technological parameters of the equipment that is a part of the continuous mixing complex according to the set productivity, recipe and requirements to the mixture homogeneity.

Controlled synthesis of multifunctional coatings by micro-arc oxidation method

The article is devoted to the development of the methodology for the controlled synthesis of protective coatings by the micro-arc oxidation method in order to improve the efficiency of this technology and the quality of the obtained oxide layers. Methodology includes a mathematical model of a galvanic cell based on an equivalent electrical circuit, as well as a model of the interconnections between the technological parameters of the micro-arc oxidation (MAO) process and the properties of the obtained oxide layers based on graph theory. The indicated dependences are formalized using methods of regression and correlation analysis of experimental data. A technique for the controlled synthesis of MAO coatings using the obtained regression equations is proposed. The structure and functioning algorithm of an intelligent automated system for the controlled synthesis of MAO coatings are developed. A prototype of this system was used to obtain experimental dependences of reaction parameters on the influence parameters of the micro-arc oxidation process.

Influence of Pressure and Temperature on the Strength Properties of a Laminate Produced by the RTM Method

This paper discusses the effect of pressure on the content of microvoids and defects inside laminates fabricated under different pressures, by vacuum methods. Two basic vacuum methods resin transfer molding (RTM) and vacuum bag method were used in this paper. A glass mat with an alignment angle of (0□/90□) and a mass of 450 g/cm2 was used to produce the laminate, and a polymer resin was used as the matrix. Special attention was paid to the technological parameters of both processes. A mathematical analysis of the most important parameters which include flow rate, permeability, and gelation temperature has been carried out. In addition, the resin temperature is used to reduce the viscosity of the resin to facilitate its flow through the reinforcement, and in the final stage of production to control the chemical reactions occurring in the mold. The pressure is chosen so that the resin flow is continuous. The synchronization of these two parameters and the measurement of the time in which they occur are called the “cure cycle”. In the final step of the study, the composite was subjected to a static tensile test, using specimens of two different dimensions (scale effect) to evaluate the effect of microvoids and microcracks created by the processes on the strength of the material.