scholarly journals Spectroscopic investigations of polycrystalline InxSb20−xAg10Se70 (0 ⩽ × ⩽ 15) multicomponent chalcogenides

2016 ◽  
Vol 34 (4) ◽  
pp. 794-799 ◽  
Author(s):  
Rita Sharma ◽  
Shaveta Sharma ◽  
Praveen Kumar ◽  
Ravi Chander ◽  
R. Thangaraj ◽  
...  

AbstractThe composition dependence of physical properties of chalcogenides has recently been studied for their phase change properties and energy conversion. In the present work, we report the structure, composition, optical and Raman spectroscopy results for bulk polycrystalline InxSb20−xAg10Se70 (0 ⩽ × ⩽ 15) samples. The phase quantification and composition have been studied by using XRD and EDX techniques. The alloy composition up to 5 at.% of indium resulted in crystallization of AgSbSe2, while further increase in In content favored the formation of another chalcopyrite AgInSe2 phase yielding the solid solutions for this alloy system. A decrease in band gap up to x = 5 followed by its increase with an increase in indium concentration has been observed. The variations in shape and position of characteristic Raman bands has been used for understanding the structural modifications of the network with the variation in indium content.

1981 ◽  
Vol 7 ◽  
Author(s):  
N. Q. Lam ◽  
H. Wiedersich

ABSTRACTModifications of subsurface alloy composition by bombardment with ions of several keV energy were investigated theoretically, using a phenomenological model which includes the effects of various processes, such as preferential sputtering, displacement mixing, Gibbsian adsorption, radiation-enhanced diffusion, and radiationinduced segregation. The nonuniformity of damage rates, resulting from slow-down of the incoming ions, was also taken into account. The alloy composition evolution in time and space was calculated numerically for different temperatures, using concentrated Ni-Cu as a model alloy system. A good qualitative agreement between the present model calculations and recent experimental measurements was obtained.


2017 ◽  
Vol 693 ◽  
pp. 631-641 ◽  
Author(s):  
R. Jemai ◽  
R. M'nassri ◽  
A. Selmi ◽  
H. Rahmouni ◽  
K. Khirouni ◽  
...  

2021 ◽  
Vol 612 ◽  
pp. 412896
Author(s):  
Rittwick Mondal ◽  
Yumnam Bonney Singh ◽  
Anindya Sundar Das ◽  
Soumyajyoti Kabi ◽  
Loitongbam Surajkumar Singh ◽  
...  

ChemInform ◽  
2004 ◽  
Vol 35 (32) ◽  
Author(s):  
J. Cwik ◽  
T. Palewski ◽  
K. Nenkov ◽  
N. V. Tristan ◽  
J. Warchulska ◽  
...  

2012 ◽  
Vol 28 (05) ◽  
pp. 1012-1020 ◽  
Author(s):  
LI Lan ◽  
◽  
HU Geng-Shen ◽  
LU Ji-Qing ◽  
LUO Meng-Fei

2018 ◽  
Vol 56 (1A) ◽  
pp. 197
Author(s):  
Nguyen Hoang Tuan

In this study, we present some results on the structure and properties of the solid solution of Bi0.5K0.5TiO3– BiFeCoO3 (BKT – BFCO) by Sol-gel method. Crystal structures of BKT – BFCO solid solutions were studies by XRD and Raman spectroscopy. The results were in good agreement with the previous reports of Bi0.5K0.5TiO3– BiFeO3 (BKT – BFO) and Bi0.5K0.5TiO3 – BiCoO3 (BKT – BCO) solid solutions. The magnetic properties were investigated via unsaturated M-H loop, which showed the competition of paramagnetic and antiferromagnetic ordering in BKT – BFCO. However, differing from the BKT – BFO and BKT – BCO solid solutions, the unclear values of saturated magnetism in BKT – BFCO raised the unexplained question, which needed further studies.


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