Kristall- und Molekülstruktur von bis -Methallylnickel Ni[(CH2)2C · CH]2
1965 ◽
Vol 122
(1-6)
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pp. 60-72
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Abstract The crystal structure of bis-methallylnickel has been determined from three-dimensional x-ray diffraction data. The space group is P21/c-C5 2h with α = 6.05; 6 = 13,48; c = 5.83 Å; β = 117.1°. The unit cell contains 2 molecules with Ni in centres of symmetry. The methallyl groups are symmetrically bonded to the nickel in an anti-sandwich arrangement. This causes the intramolecular symmetry to be 2/m. The methallyl groups are found to be nonplanar and the Ni-C bonds are quite short (average 2.02 Å).
1973 ◽
Vol 28
(7-8)
◽
pp. 426-428
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