Electrical Mobilities and Tracer-diffusion Coefficients of the Na and Tl Ions in the Molten (Na — Tl)NO3 System

1967 ◽  
Vol 22 (8) ◽  
pp. 1171-1176 ◽  
Author(s):  
Sandro Forcheri ◽  
Vittoriano Wagner
Keyword(s):  
Diffusion Coefficients ◽  
Tracer Diffusion ◽  
Significant Feature ◽  
Rapid Variation ◽  
Polarization Model ◽  
Diffusion Technique ◽  
Zone Electrophoresis ◽  
Ionic Mobilities ◽  
Tracer Diffusion Coefficients ◽  
And Diffusion

The ionic mobilities and the diffusion coefficients of Na and Tl in the (Na-Tl) NO3 system have been determined by means of a zone electrophoresis and diffusion technique. The most significant feature of the Na mobility isotherm is its rapid variation with composition in the NaNO3 rich region.The diffusion coefficients of both cations have been found to depend rather weakly on composition. The electrical and diffusional mobilities of both cations show trends opposite to that of the fluidity.These results are discussed in terms of the anion polarization model.

Site Preference and Diffusion in Ni3Al Alloyed with Ir, Ta or Re at 1200°C

2010 ◽  
Vol 297-301 ◽  
pp. 1322-1327 ◽  
Author(s):  
N. Garimella ◽  
H.J. Choi ◽  
Yong Ho Sohn
Keyword(s):  
Diffusion Coefficients ◽  
Tracer Diffusion ◽  
Site Preference ◽  
Solid Diffusion ◽  
Ordered Intermetallic ◽  
Ternary Alloying ◽  
Tracer Diffusion Coefficients ◽  
Interdiffusion Coefficients ◽  
And Diffusion

Diffusion in L12-Ni3Al with ternary alloying additions of Ir, Ta and Re was investigated at 1200°C using solid-to-solid diffusion couples, and examined with respect to site preference in ordered intermetallic compound. In addition to determination of average ternary interdiffusion coefficients [1-3], average effective interdiffusion coefficients were determined directly from the experimental concentration profiles. Ni has the largest magnitude of average effective interdiffusion coefficient, followed by Al, Ir, Re and Ta. The average effective interdiffusion coefficients for Ir, Re and Ta are much smaller than those for Ni and Al. Tracer diffusion coefficients determined by extrapolation technique, and available literature also followed the same trend. The relative tendency of Ni, Al, Ir, Re and Ta to occupy the -Ni and -Al sites are correlated to these diffusion coefficients, with due consideration for diffusion mechanisms and coordination of atoms.

Non-Stoichiometry and Cation Tracer Diffusion Studies in the Magnetite-UlvÖSpinel Solution, (Fe,Ti)3-δO4

1994 ◽  
Vol 369 ◽  
Author(s):  
Sanjeev Aggarwal ◽  
Rudiger Dieckmann
Keyword(s):  
Diffusion Coefficients ◽  
Tracer Diffusion ◽  
Oxygen Activity ◽  
Spinel Solid Solution ◽  
Low Oxygen ◽  
Cation Diffusion ◽  
Deviation From Stoichiometry ◽  
Diffusion Studies ◽  
Tracer Diffusion Coefficients ◽  
Point Defect Structure

AbstractCation diffusion in the spinel solid solution (Fe1-xTix)3-δO4 (0≤ x ≤ 0.3) was investigated at 1200 ºC as a function of oxygen activity, aO2 and cationic composition, x. At different cationic compositions, cation tracer diffusion coefficients, D*Me of Me = Fe and Ti were measured as a function of oxygen activity. Plots of log DMe vs. loga0 show V-shaped curves, indicating that different types of point defects prevail at high anc low oxygen activities. Thermogravimetric experiments were conducted, using a high resolution microbalance, to determine the deviation from stoichiometry in (Fe1-xTix)3-δO4 at 1200 °C. δversus log aO2 curves are S-shaped. An analysis of the oxygen activity dependences of thecation diffusion coefficients and the deviation from stoichiometry with regardto the point defect structure suggests that at high oxygen activities cation vacancies are the predominant defects governing the deviation from stoichiometry and the diffusion ofcations. At low oxygen activities, and at small values of x, cation interstitials determine the deviation from stoichiometry, while they dominate for 0 ≤ x ≤ 0.3 inthe cation diffusion.

Experimental Determination of Statistical Properties of Two-Phase Turbulent Motion

1960 ◽  
Vol 82 (3) ◽  
pp. 609-621 ◽  
Author(s):  
S. L. Soo ◽  
H. K. Ihrig ◽  
A. F. El Kouh
Keyword(s):  
Gas Phase ◽  
Tracer Diffusion ◽  
Statistical Properties ◽  
Solid Particles ◽  
Turbulent Motion ◽  
Two Phase ◽  
Gaseous State ◽  
Diffusion Technique ◽  
And Diffusion

Experimental methods for the determination of certain statistical properties of turbulent conveyance and diffusion of solid particles in a gaseous state are presented. Methods include a tracer-diffusion technique for the determination of gas-phase turbulent motion and a photo-optical technique for the determination of motion of solid particles. Results are discussed and compared with previous analytical results.

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