Röntgen-Beugungsuntersuchungen an geschmolzenem Tellur / X-ray Diffraction Study of Molten Tellurium

1975 ◽  
Vol 30 (2) ◽  
pp. 235-241 ◽  
Author(s):  
W. Hoyer ◽  
E. Thomas ◽  
M. Wobst

Abstract X-ray Diffraction Study of Molten Tellurium An X-ray diffraction apparatus with focusing geometry used for the investigation of free surfaces of melts and a computer programme for the analysis of scattering intensities are discribed. The results of our measurements on molten tellurium at 480, 550 and 620 °C are presented and compared with a model of the temperature change of the short range order in molten tellurium as described by Cabane, Tourand and Breuil 14-17. The important result is that the number of nearest neighbours is approximately 3 at all the 3 temperatures. This suggests that the short range order is changing at the melting point from a chain structure to an antimony-like structure.

1981 ◽  
Vol 36 (8) ◽  
pp. 880-885 ◽  
Author(s):  
W. Hoyer ◽  
B. Kunsch ◽  
M. Suda ◽  
E. Wieser

Abstract Neutron scattering results on Se1-xTex melts (x = 0.3, 0.6, 0.8) obtained at 460 °C are combined with earlier X-ray diffraction data. The behaviour of the number and distance of nearest neighbours is discussed with respect to chemical short-range order and transition from twofold to three-fold coordination. For Se70Te30 the radial concentration correlation function 4πr2 ρcc(r) has been evaluated. It shows clearly the preferred formation of unlike pairs (Se-Te) within the chains.


2002 ◽  
Vol 71 (10) ◽  
pp. 2456-2458 ◽  
Author(s):  
Dilip Kumar Saha ◽  
Toetsu Shishido ◽  
Ken-ichi Ohshima

1987 ◽  
Vol 42 (1) ◽  
pp. 7-12 ◽  
Author(s):  
A. Müller ◽  
E. Bühler ◽  
P. Lamparter ◽  
S. Steeb

Amorphous Co25Ti75 could be produced using the melt-spin-technique. A neutron- and a X-ray-diffraction experiment was performed. Assuming SNC ≡ 0 the partial Bhatia Thornton structure factors SNN and SCC as well as the partial coordination numbers were calculated. The discussion yields the atomic distances and the chemical short range order parameters.


2003 ◽  
Vol 72 (7) ◽  
pp. 1670-1674 ◽  
Author(s):  
Dilip Kumar Saha ◽  
Toetsu Shishido ◽  
Hiroshi Iwasaki ◽  
Ken-ichi Ohshima

1995 ◽  
Vol 6 (5-8) ◽  
pp. 593-596 ◽  
Author(s):  
N. Schlorke ◽  
J. Weissmüller ◽  
W. Dickenscheid ◽  
H. Gleiter

1987 ◽  
Vol 42 (5) ◽  
pp. 507-510 ◽  
Author(s):  
E. Bühler ◽  
P. Lamparter ◽  
S. Steeb

By means of X-ray diffraction in transmission the molten MgxZn(1oo-x)-alloys (x = 0, 8, 15, 30, 40, 50, 60, 70, 73, 80, 90, 100) were investigated and the total structure factor S (Q) , the total pair correlation function, the number of nearest neighbours as well as the atomic distances were evaluated. For 30 ≦ x ≦ 80 a premaximum in S (Q) was observed which is caused by chemical short range order. The comparison of the premaximum of the Mg70Zn30-melt with that of the corresponding amorphous alloy shows that within the melt the chemical short range order amounts to about 40% of that of the amorphous alloy.


2003 ◽  
Vol 72 (1) ◽  
pp. 107-110 ◽  
Author(s):  
Timbangen Sembiringa ◽  
Dilip Kumar Saha ◽  
Miwako Takahashi ◽  
Toetsu Shishido ◽  
Ken-ichi Ohshima

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