Über Erdalkalimetall-Oxocuprate. VI.
1972 ◽
Vol 27
(3)
◽
pp. 296-301
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Keyword(s):
X Ray
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The preparation and chemical properties of barium-oxocuprat (I) inclusive the results of the crystal structure determination by single crystal X-ray investigations are described. BaCu2O2 crystallizes isotypically with SrCu2O2 . (a = 5.72 and c = 10.06 Å. Spacegroup : D194h - 141/amd.) The influence of the bigger Ba2⨁-ion on the oxigenconfiguration surrounding the cations is discussed. It seems that the stretched O - Cu - O-dumbell is an invariable structural element in the oxocompounds of copper (I), which is shown by comparison of already known oxocuprates (I) . Only the way of interchainment varies evidently with stoichiometry.
1998 ◽
Vol 213
(12)
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Keyword(s):
1992 ◽
Vol 100
(2)
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pp. 341-355
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2009 ◽
Vol 64
(8)
◽
pp. 985-988
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2017 ◽
Vol 81
(5)
◽
pp. 1063-1071
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2007 ◽
Vol 62
(5)
◽
pp. 705-710
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1998 ◽
Vol 135
(2)
◽
pp. 282-292
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