Untersuchungen an Polypseudohalogeniden, VI / Studies on the Polypseudohalides, VI
1989 ◽
Vol 44
(6)
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pp. 637-640
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Keyword(s):
The new compound Na[I(CN)2] · 2 H2O can be prepared by addition of iodine to a concentrated aqueous solution of sodium cyanide. It crystallizes in the monoclinic space group P21/c with a = 1044.0(2), b = 480.2(2), c = 730.2(2) pm, β = 95.94(2)° and Z = 2. The crystal structure has been refined to Rf = 0.027 for 692 reflections.The structure may be described as a layer-like package of cations Na+, water molecules and trihalide-analogous anions [I(CN)2]-. The anion is strictly linear at the I atom and nearly linear at the C atoms with φ(I-C-N) = 176.2° and d(I-C) = 231.1, d(C-N) = 110.6 pm. The cation is surrounded by a slightly distorted octahedron of nitrogen and oxygen atoms with d(Na · · ·N) = 263.8, d(Na · · · O) = 242.0, 242.8 pm
1995 ◽
Vol 59
(394)
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pp. 159-162
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Keyword(s):
1988 ◽
Vol 43
(2)
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pp. 149-152
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Keyword(s):
Keyword(s):
1986 ◽
Vol 51
(11)
◽
pp. 2521-2527
◽
1967 ◽
Vol 45
(20)
◽
pp. 2297-2302
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Keyword(s):
1996 ◽
Vol 51
(10)
◽
pp. 1469-1472
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1977 ◽
Vol 145
(5-6)
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