Kristallstrukturuntersuchung des Kupfer-Cadmium-Oxovanadats CuCdVO4 / Crystal Structure Investigation of the Copper Cadmium Oxovanadate CuCdVO4
1995 ◽
Vol 50
(6)
◽
pp. 871-874
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Single crystals of CuCdVO4 have been prepared by CO2-LASER techniques. X -ray investigations of the black single crystals led to orthorhombic symmetry, space group D2h17-Cmcm , a = 5.921(1), b = 9.065(4), c = 6.633(2) Å, Z = 4. CuCdVO4 represents the first example of a quaternary oxide containing cadmium and copper(I). Compared to AgCdVO4, CuCdVO4 shows a different linkage of the VO4 and CuO4 tetrahedra, explaining the missing isotypy of these com pounds.
1995 ◽
Vol 50
(8)
◽
pp. 1146-1150
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1995 ◽
Vol 50
(11)
◽
pp. 1653-1657
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