N–O Bond Cleavage During the Deprotonation of N,O-Bis(trimethylsilyl)hydroxylamine
2008 ◽
Vol 63
(3)
◽
pp. 339-341
◽
Keyword(s):
X Ray
◽
The reaction of N,O-bis(trimethylsilyl)hydroxylamine with potassium hydride in pentane affords a product of the formula {K6[OSiMe3]4[ON(SiMe3)2]2}, resulting from deprotonation followed by N-O bond cleavage and 1,2-silylshift. The compound was characterised by elemental analysis and by single crystal X-ray diffraction. The aggregate consists of a K3O3 bis-cubane core, with N(SiMe3)2 groups at the oxygen atoms shared by the two cubes, andMe3Si groups attached to the four O vertices. Two weak K···N interactions are also detected in the solid state structure.
1995 ◽
Vol 50
(4)
◽
pp. 699-701
◽
Keyword(s):
2013 ◽
Vol 78
(19)
◽
pp. 9949-9955
◽
Keyword(s):
2003 ◽
Vol 68
(10)
◽
pp. 1897-1903
◽
Keyword(s):
2003 ◽
Vol 680
(1-2)
◽
pp. 165-172
◽
Keyword(s):
Keyword(s):
2012 ◽
Vol 16
(01)
◽
pp. 154-162
◽
Keyword(s):