A new luminescent metal-organic framework with 2,6-di(1H-imidazol-1-yl)naphthalene and biphenyl-3,4′,5-tricarboxylic acid

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Zhi-Qiang Liu ◽  
Ran-Ran Liu ◽  
Heng-Hui Jin ◽  
Long-Wen Lei ◽  
Zhi-Ping Wang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Chain Structure ◽  
Tricarboxylic Acid ◽  
Strong Emission ◽  
X Ray Crystallography ◽  
3D Network ◽  
Metal Organic ◽  
Photoluminescence Studies ◽  
Organic Framework

Abstract In this work, a novel metal-organic framework (MOF) based on 2,6-di(1H-imidazol-1-yl)naphthalene (L) and biphenyl-3,4′,5-tricarboxylic acid (H3bptc), namely [Co(L)(Hbptc)(H2O)] (1), has been prepared. 1 has a distinct infinite chain structure, further linked together by winding interactions to give the three-dimensional (3D) network structure. 1 was characterized by X-ray crystallography, infrared spectra (IR) spectroscopy, elemental and thermal analysis. Photoluminescence studies revealed that 1 shows a strong emission at 361 nm upon excitation at 290 nm at room temperature. Moreover, 1 can efficiently detect Fe3+ ions by luminescence quenching.

scholarly journals An amino-functionalized three-dimensional cadmium metal–organic framework: Synthesis, characterization and excellent fluorescence sensing of Fe3+

2021 ◽  
pp. 174751982110189
Author(s):  
Jifa Yin ◽  
Youjie Han ◽  
Hongmei Zhu ◽  
Ye Tian
Keyword(s):  
Transition Metal ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Tricarboxylic Acid ◽  
Fluorescence Sensing ◽  
Quenching Efficiency ◽  
Cadmium Metal ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

An amino-functionalized three-dimensional cadmium metal–organic framework, [Cd1.5(L)(DMF)]·2H2O (complex 1) L = H3TTCA-NH2 = 2′-amino-[1,1′:3′,1″-terphenyl]-4,4″,5′-tricarboxylic acid), is successfully synthesized under solvothermal conditions and structurally characterized. Interestingly, as a transition metal organic framework, the cadmium metal–organic framework exhibits favorable luminescence properties. In addition, the cadmium metal–organic framework reveals excellent selective and sensitive fluorescence sensing for the recognition of Fe3+ with high quenching efficiency ( Ksv = 3.340 × 103 M−1), demonstrating that the cadmium metal–organic framework can be used as a potential sensor for Fe3+.

scholarly journals Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Omid T. Qazvini ◽  
Ravichandar Babarao ◽  
Shane G. Telfer
Keyword(s):  
Carbon Dioxide ◽  
Density Functional ◽  
Metal Organic Framework ◽  
Density Functional Theory Calculations ◽  
Time Lags ◽  
X Ray Crystallography ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
Short Time ◽  
Organic Framework

AbstractEfficient and sustainable methods for carbon dioxide capture are highly sought after. Mature technologies involve chemical reactions that absorb CO2, but they have many drawbacks. Energy-efficient alternatives may be realised by porous physisorbents with void spaces that are complementary in size and electrostatic potential to molecular CO2. Here, we present a robust, recyclable and inexpensive adsorbent termed MUF-16. This metal-organic framework captures CO2 with a high affinity in its one-dimensional channels, as determined by adsorption isotherms, X-ray crystallography and density-functional theory calculations. Its low affinity for other competing gases delivers high selectivity for the adsorption of CO2 over methane, acetylene, ethylene, ethane, propylene and propane. For equimolar mixtures of CO2/CH4 and CO2/C2H2, the selectivity is 6690 and 510, respectively. Breakthrough gas separations under dynamic conditions benefit from short time lags in the elution of the weakly-adsorbed component to deliver high-purity hydrocarbon products, including pure methane and acetylene.

Three-dimensional hierarchical C-Co-N/Se derived from metal-organic framework as superior cathode for Li-Se batteries

2017 ◽  
Vol 363 ◽  
pp. 103-109 ◽  
Author(s):  
Jiarui He ◽  
Weiqiang Lv ◽  
Yuanfu Chen ◽  
Jie Xiong ◽  
Kechun Wen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Metal Organic ◽  
Organic Framework

Electron transitions in a Ce(iii)-catecholate metal–organic framework

2022 ◽  
Author(s):  
Julia G. Knapp ◽  
Debmalya Ray ◽  
Paul B. Calio ◽  
Megan C. Wasson ◽  
Thais R. Scott ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Electron Transitions ◽  
Metal Organic ◽  
Organic Framework

Competitive electron transitions are present in a rare three-dimensional Ce(iii)-catecholate metal–organic framework.

Li-based MOF-derived multifunctional PEO polymer solid-state electrolyte for lithium energy storage

2022 ◽  
Author(s):  
Xiang Han ◽  
Tiantian Wu ◽  
Lanhui Gu ◽  
Dian Tian
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework containing Li-oxygen clusters, namely {[Li2(IPA)]·DMF}n (1) (H2IPA = isophthalic acid), has been constructed under solvothermal conditions. The Li-based MOF can be applied to lithium energy...

Three-Dimensional Hierarchical Architectures Derived from Surface-Mounted Metal-Organic Framework Membranes for Enhanced Electrocatalysis

2017 ◽  
Vol 129 (44) ◽  
pp. 13969-13973 ◽  
Author(s):  
Gan Jia ◽  
Wen Zhang ◽  
Guozheng Fan ◽  
Zhaosheng Li ◽  
Degang Fu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Metal Organic ◽  
Hierarchical Architectures ◽  
Organic Framework

A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU

2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu
Keyword(s):  
Thermal Stability ◽  
Benzoic Acid ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crystalline Material ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.

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