scholarly journals Geochemistry of Sarmatian volcanic rocks in the Tokaj Mts (NE Hungary) and their relationship to hydrothermal mineralization

2010 ◽  
Vol 53 (4) ◽  
pp. 377-403 ◽  
Author(s):  
Péter Kiss ◽  
Katalin Gméling ◽  
Ferenc Molnár ◽  
Zoltán Pécskay
Author(s):  
S. A. Maliutin

Areas of distribution of alkaline granitoids in southernKazakhstanhave been identified, most of which are located within the Kendyktas-Chu-Ili-Betpakdalin uranium-bearing province, traditionally considered as Late Devonian-early Carboniferous. Arguments in favor of late Paleozoic age of alkaline rocks have been given. The proximity of the petrographic composition, petrochemical and geochemical features of the alkaline granites of the Chu-Ili-West-Balkhash area and late Paleozoic alkaline granites of the Zailiysky area has been established, confirming their age and continental rift origin. Similarity in the development of magmatism and hydrothermal mineralization of ore-bearing volcanic structures of the Chui area (Kurmanshitinskoe) and North-Western Chingiz (Ulkentuz and Dostar) has been revealed. In these structures, Devonian volcanic rocks are interspersed with subvolcanic bodies of comendites and later dikes of microgabbrodiorites and microdiorites. The hydrothermal mineralization of these structures took place in multiple stages. The early stage includes secondary quartzites, which developed in Devonian volcanogenic rocks. Comendite is associated with K-feldspated and albitized rocks, as well as with zones of rare-metal (Zr, Nb, Th, U and TR) Fe-Mg metasomatites that originated in the middle stage. In the later stage, after the introduction of microgabbrodiorite dikes, berezites with U-Mo mineralization formed. Comendites in the structures of the North-Western Chingiz break through the deposits D2-3 and D3-C1 and are considered to be the comagmatic alkaline granites of the neighboring late Paleozoic massifs (Tleumbet and Kuyrektykol). The noted similarity may also indicate that the Chui area comendites are likely to be dated to the late Paleozoic age. Examples have been given to the superposition of berezites and U-Mo mineralization on the late Paleozoic granosyenites, which are widespread in the Kurdai volcanic structure, as well as on the alkaline granites of Karasai volcanic structure. Their age may also be late Paleozoic. Additional research has been recommended for the final conclusions on the age of alkaline rocks and uranium mineralization.


Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.


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