Fabrication of Microfluidic Devices for the study of Ion transport through Single-Walled Carbon Nanotubes

MRS Advances ◽  
2016 ◽  
Vol 1 (28) ◽  
pp. 2085-2090 ◽  
Author(s):  
Khadija Yazda ◽  
Sophie Roman ◽  
Saïd Tahir ◽  
François Henn ◽  
Vincent Jourdain

ABSTRACTStudying the transport of ions through single-walled carbon nanotubes (SWCNTs) necessitate the fabrication of a fluidic setup integrating carbon nanotubes. In this article, we report on the development of a simple fabrication protocol of SWCNTs fluidic devices. This protocol allows an excellent control of the system features and of the experimental conditions compared with previously published protocols. Our protocol based on the use of the popular SU-8, the preferred photoresist for the fabrication of high-aspect-ratio patterns, allows one to prepare sealed microfluidic devices incorporating one or several tens of individual carbon nanotubes of length between 20 and 80 µm.

Nanoscale ◽  
2017 ◽  
Vol 9 (33) ◽  
pp. 11976-11986 ◽  
Author(s):  
Khadija Yazda ◽  
Saïd Tahir ◽  
Thierry Michel ◽  
Bastien Loubet ◽  
Manoel Manghi ◽  
...  

SWCNTs of diameter of 1.2 to 2 nm can show a linear or a voltage-activatedI–Vdependence.


Carbon ◽  
2014 ◽  
Vol 79 ◽  
pp. 529-537 ◽  
Author(s):  
André O. Monteiro ◽  
Pedro M.F.J. Costa ◽  
Paulo B. Cachim ◽  
David Holec

Nanoscale ◽  
2015 ◽  
Vol 7 (15) ◽  
pp. 6745-6753 ◽  
Author(s):  
Taeheon Lee ◽  
Byunghee Kim ◽  
Sumin Kim ◽  
Jong Hun Han ◽  
Heung Bae Jeon ◽  
...  

We synthesized p(FMA-co-DMAEMA) for the dispersion of SWCNTs while maintaining their high aspect ratios.


2018 ◽  
Vol 51 ◽  
pp. 24-38 ◽  
Author(s):  
Ahmed Hamidi ◽  
Mohamed Zidour ◽  
Khaled Bouakkaz ◽  
Tayeb Bensattalah

The non-local Timoshenko beam theory has been implemented to investigate the free vibration of armchair single-walled carbon nanotubes embedded in elastic medium including the thermal effects. The mechanical properties of nano-composite (carbon nanotubes and polymer matrix) are treated as functions of temperature change and the analytical solution is derived according to the governing equations of non-local Timoshenko beam models. The equivalent Young’s modulus and shear modulus for armchair single-walled carbon nanotubes are derived using an energy-equivalent model. Influence of small-scale coefficient, vibrational mode number, matrix of nano-composite and aspect ratio on the frequency ratio of the armchair single-walled carbon nanotubes including the thermal effect are studied and discussed. The research work reveals the significance of the small-scale coefficient, the vibrational mode number, the elastic medium and the aspect ratio on the frequency ratio. It is also demonstrated that some properties of free vibrations of single-walled carbon nanotubes are dependent on the change of temperature.


MRS Advances ◽  
2016 ◽  
Vol 1 (28) ◽  
pp. 2079-2084
Author(s):  
Khadija Yazda ◽  
Saïd Tahir ◽  
Thierry Michel ◽  
François Henn ◽  
Vincent Jourdain

ABSTRACTThe electrophoretic transport of ions through single walled carbon nanotubes (SWCNTs) of diameters between 1.2 and 1.8 nm was studied for different monovalent chloride salts using microfluidic devices incorporating either a single or few SWCNTs in parallel. The ionic conductance was found to be about one order of magnitude higher than would be expected from simple bulk electrophoresis without any surface effect. Importantly, the ionic conductance measured for different cations did not scale with their bulk electrophoretic mobility thus indicating a selective cation transport through these sub-2 nm SWCNTs. The transport of Na+ was notably found to be favored in comparison to that of Li+, K+ and Cs+. These results highlight the influence of steric and surface effects induced by the nano-confinement on the transport of ions through sub-2 nm SWCNTs.


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