Advances In High-Efficiency, Multiple-Gap, Multijunction Amorphous Silicon-Based Alloy Thin-Film Solar Cells

1989 ◽  
Vol 149 ◽  
Author(s):  
S. Guha

ABSTRACTIt is now well-recognized that multijunction, multi-gap amorphous silicon-based alloy solar cells offer the attractive advantage of obtaining high efficiency with good long-term stability. In this paper we review the progress made in this field. Research directions to further improve the efficiency are discussed.

2005 ◽  
Vol 862 ◽  
Author(s):  
Scott J. Jones ◽  
Joachim Doehler ◽  
Tongyu Liu ◽  
David Tsu ◽  
Jeff Steele ◽  
...  

AbstractNew types of transparent conductive oxides with low indices of refraction have been developed for use in optical stacks for the amorphous silicon (a-Si) solar cell and other thin film applications. The alloys are ZnO based with Si and MgF added to reduce the index of the materials through the creation of SiO2 or MgF2, with n=1.3-1.4, or the addition of voids in the materials. Alloys with 12-14% Si or Mg have indices of refraction at λ=800nm between 1.6 and 1.7. These materials are presently being used in optical stacks to enhance light scattering by Al/multi-layer/ZnO back reflectors in a-Si based solar cells to increase light absorption in the semiconductor layers and increase open circuit currents and boost device efficiencies. In contrast to Ag/ZnO back reflectors which have long term stability issues due to electromigration of Ag, these Al based back reflectors should be stable and usable in manufactured PV products. In this manuscript, structural properties for the materials will be reported as well as the performance of solar cell devices made using these new types of materials.


2019 ◽  
Vol 9 (20) ◽  
pp. 4393 ◽  
Author(s):  
Jien Yang ◽  
Songhua Chen ◽  
Jinjin Xu ◽  
Qiong Zhang ◽  
Hairui Liu ◽  
...  

Perovskite solar cells (PSCs) employing organic-inorganic halide perovskite as active layers have attracted the interesting of many scientists since 2009. The power conversion efficiency (PCE) have pushed certified 25.2% in 2019 from initial 3.81% in 2009, which is much faster than that of any type of solar cell. In the process of optimization, many innovative approaches to improve the morphology of perovskite films were developed, aiming at elevate the power conversion efficiency of perovskite solar cells (PSCs) as well as long-term stability. In the context of PSCs research, the perovskite precursor solutions modified with different additives have been extensively studied, with remarkable progress in improving the whole performance. In this comprehensive review, we focus on the forces induced by additives between the cations and anions of perovskite precursor, such as hydrogen bonds, coordination or some by-product (e.g., mesophase), which will lead to form intermediate adduct phases and then can be converted into high quality films. A compact uniform perovskite films can not only upgrade the power conversion efficiency (PCE) of devices but also improve the stability of PSCs under ambient conditions. Therefore, strategies for the implementation of additives engineering in perovskites precursor solution will be critical for the future development of PSCs. How to manipulate the weak forces in the fabrication of perovskite film could help to further develop high-efficiency solar cells with long-term stability and enable the potential of future practical applications.


2020 ◽  
Vol 1 (9) ◽  
pp. 3439-3448
Author(s):  
Mailde S. Ozório ◽  
Willian X. C. Oliveira ◽  
Julian F. R. V. Silveira ◽  
Ana Flávia Nogueira ◽  
Juarez L. F. Da Silva

Despite high photo-conversion efficiency, the short long-term stability and toxicity issues have prevented lead-based perovskites from becoming the standard in high efficiency solar cells.


Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 775
Author(s):  
Yinghui Wu ◽  
Dong Wang ◽  
Jinyuan Liu ◽  
Houzhi Cai

Perovskite solar cells (PSCs) are the most promising substitute for silicon-based solar cells. However, their power conversion efficiency and stability must be improved. The recombination probability of the photogenerated carriers at each interface in a PSC is much greater than that of the bulk phase. The interface of a perovskite polycrystalline film is considered to be a defect-rich area, which is the main factor limiting the efficiency of a PSC. This review introduces and summarizes practical interface engineering techniques for improving the efficiency and stability of organic–inorganic lead halide PSCs. First, the effect of defects at the interface of the PSCs, the energy level alignment, and the chemical reactions on the efficiency of a PSC are summarized. Subsequently, the latest developments pertaining to a modification of the perovskite layers with different materials are discussed. Finally, the prospect of achieving an efficient PSC with long-term stability through the use of interface engineering is presented.


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