AZO Polymers for Reversible Optical Storage

1992 ◽  
Vol 277 ◽  
Author(s):  
A. Natansohn ◽  
P. Rochon ◽  
J. Gosselin ◽  
S. Xie

ABSTRACTAmorphous high-Tg polymers films containing electron-donor-electronacceptor substituted azobenzene groups can be used as reversible optical storage materials. Optical information can be “written” on the film with a polarized argon laser beam and “read” with a low power HeNe laser. Erasing can be performed with a circularly polarized writing beam. A significant number of writing/erasing cycles can be performed on the same spot. Potential applications in optical memory, holographic storage, waveguides and second harmonic generation are discussed.

1995 ◽  
Vol 73 (11) ◽  
pp. 1773-1778 ◽  
Author(s):  
Mei-Sing Ho ◽  
A. Natansohn ◽  
C. Barrett ◽  
P. Rochon

Poly[4′-[[(2-methacryloyloxy)ethyl]ethylamino]azobenzene] (pMAEA) was prepared. Its reversible optical storage properties were studied and compared with the properties of previously reported poly[4-(2-methacryloyloxy)ethylazobenzene] (pMEA) and poly[4-nitrophenyl-4′-[[2-(methacryloyloxy)ethyl]ethyl-amino]phenyldiazene] (pDR1M). The effect of the dipole moment of the azobenzene moiety on the optical storage properties was studied by comparing the photochemically induced birefringence "writing" and "relaxation" behaviors. The writing and relaxation rates are both in the order pDR1M > pMAEA > pMEA. In addition, pDR1M, which contains donor/acceptor substituents in the azobenzene side chain, exhibits the highest saturation level of optically induced birefringence. The fraction of birefringence conserved after relaxation is lowest for pMEA, which has no donor/acceptor substituents in the azobenzene side chain, and highest for pDR1M. Keywords: polymers, azobenzene type, birefringence, photochemically induced orientation, reversible optical storage.


2021 ◽  
Author(s):  
Yan-Lei Lu ◽  
Wen-Long Lan ◽  
Wei Shi ◽  
Qionghua Jin ◽  
Peng Cheng

Photo-induced variation of magnetism from ligand-based electron transfer have been extensively studied because of their potential applications in magneto-optical memory devices, light-responsive switches, and high-density information storage materials. In this...


1995 ◽  
Vol 28 (18) ◽  
pp. 6124-6127 ◽  
Author(s):  
M. S. Ho ◽  
A. Natansohn ◽  
P. Rochon
Keyword(s):  

Author(s):  
Wan Zhang ◽  
Baining Ni ◽  
Hongkun Li ◽  
Yonggang Yang ◽  
Yongfang Li ◽  
...  

Circularly polarized luminescence (CPL) materials have attracted increasing interest due to their wide potential applications. However, achieving CPL-active materials with both large dissymmetry factor (glum) and high quantum yield (F)...


Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 975 ◽  
Author(s):  
Peizhen Qiu ◽  
Taiguo Lv ◽  
Yupei Zhang ◽  
Binbin Yu ◽  
Jiqing Lian ◽  
...  

Realizing multiple beam shaping functionalities in a single plasmonic device is crucial for photonic integration. Both plasmonic Bessel-like beams and bottle beams have potential applications in nanophotonics, particularly in plasmonic based circuits, near field optical trapping, and micro manipulation. Thus, it is very interesting to find new approaches for simultaneous generation of surface plasmon polariton Bessel-like beams and bottle beams in a single photonic device. Two types of polarization-dependent devices, which consist of arrays of spatially distributed sub-wavelength rectangular slits, are designed. The array of slits are specially arranged to construct an X-shaped or an IXI-shaped array, namely X-shaped device and IXI-shaped devices, respectively. Under illumination of circularly polarized light, plasmonic zero-order and first-order Bessel-like beams can be simultaneously generated on both sides of X-shaped devices. Plasmonic Bessel-like beam and bottle beam can be simultaneously generated on both sides of IXI-shaped devices. By changing the handedness of circularly polarized light, for both X-shaped and IXI-shaped devices, the positions of the generated plasmonic beams on either side of device can be dynamically interchanged.


1995 ◽  
Vol 28 (12) ◽  
pp. 4179-4183 ◽  
Author(s):  
Almeria Natansohn ◽  
Paul Rochon ◽  
Mei-Sing Ho ◽  
Chris Barrett
Keyword(s):  

2021 ◽  
Author(s):  
Jian-Jun Liu ◽  
Jia-Jia Fu ◽  
Teng Liu ◽  
Chixian He ◽  
Feixiang Cheng

Photochromic materials coupled with the photoswitchable luminescence functionalities are of particular interest due to their potential applications in switches and optical memory devices. However, construct such materials, especially those with...


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