Waste Glass Leaching and Alteration Under Conditions of Open Site Tests

1996 ◽  
Vol 465 ◽  
Author(s):  
I. A. Sobolev ◽  
M. I. Ojovan ◽  
O.G Batyukhnova ◽  
N. V. Ojovan ◽  
T. D. Scherbatova

ABSTRACTThe behaviour of waste glass was investigated under open site disposal conditions. This glass was produced by vitrification of intermediate level radioactive waste from nuclear power plants. Two types of borosilicate glasses were obtained for two different reactor wastes, WWER and RBM.K. Leaching and alteration mechanisms are discussed as well as the data processing technique used for these long term tests. The decay of radionuclides was accounted for in order to obtain correct results. The leaching factors obtained can be used for the assesment of radionuclide retention. Discontinuous leaching of Cs-137 has been observed during more than 8 years testing time. The fluctuating leaching rate depends on glass composition. The average leaching rate remains within (0.4 – 4) μg/sq. sm·day.Alteration of waste glass includes the formation of surface layers and cracks on the glass surface. SEM analysis of glass was used to show these surface layers. The thickness of the layers was determined to be within 2–6 μm. The structure of these layers depends on glass composition and the interfacing environment.

2013 ◽  
Vol 284-287 ◽  
pp. 1749-1753
Author(s):  
Kyung Nam Jang ◽  
Jong Soeg Kim ◽  
Sun Chul Jeong ◽  
Kyung Heum Park ◽  
Sung Yull Hong

In nuclear power plants, there are many cables that perform safety-related functions. These cables should implement condition monitoring during the operation period in the nuclear power plant, in order to assess the remaining qualified life and extend the qualified life. In this study we focused on the indenting method which can measure the hardness of the cable jacket. This method is selected because it is non-destructive and requires short testing time and small sized equipment. In order to address the problems with the existing indenting test equipment, we developed new indenting test equipment, which could automatically move on the surface of the object cable. The newly developed equipment is designed for a small-sized and light-weight robot using wireless communication in order to implement condition monitoring in a harsh environment or locations that are inaccessible to the tester. The developed wireless cable indenting robot is composed of three parts, which are mechanical and electrical hardware parts and remote-control part. In order to analyze the degradation tendency of the cable, we prepared four thermally aged specimens and one un-aged specimen. Using the developed robot, we measured the modulus of the cable jacket of each specimen. The test data showed that the modulus of the cable jacket increased linearly as the accelerated aging time increased. From these results, we can analyze the degradation trends pertaining to cables installed in nuclear power plant according to the operation period.


1995 ◽  
Vol 412 ◽  
Author(s):  
A. S. Barinov ◽  
M. I. Ojovan ◽  
N. V. Ojovan

AbstractLong term tests of vitrified intermediate level waste from nuclear power plants were performed in a shallow ground repository as well as on an open testing area. Borosilicate glasses were tested. Radionuclide leaching differs significantly in natural conditions in contrast to laboratory behaviour. Average leaching factors were obtained for open area tests as well as for repository tests. These factors should be used for long term predictions since they take into account the real character of leaching.


1997 ◽  
Vol 506 ◽  
Author(s):  
A.S. Barinov ◽  
M.I. Ojovan ◽  
N.V. Ojovan

ABSTRACTIn the middle of 80-s the Moscow SIA “Radon” initiates a program on long term tests of vitrified intermediate level radioactive waste from nuclear power plants with different types'of reactors and with different composition of waste. Glass blocks were prepared and disposed for tests in experimental shallow ground repository and on open testing area. Borosilicate glass as matrix material is investigated in order to obtain data on real behaviour of glass [1]. The waste glass was poured in carbon steel rectangular containers therefore containers also were subjected to aqueous and atmospheric corrosion. Exposure conditions at testing site are varying depending on season. They can be described only as average parameters with some uncertainties.


2019 ◽  
pp. 68-74 ◽  
Author(s):  
V. Svidersky ◽  
V. Glukhovsky ◽  
I. Glukhovsky ◽  
T. Dashkova

This review provides a brief analysis of familiar and tested technologies of liquid radioactive waste solidification. The technologies of bituminization, vitrification and incorporation of radioactive waste into the polymer matrix are considered. The paper presents the efficiency indices of the conventional cementation technology and sets forth the results of calculating the cost of components for cementing liquid radioactive waste of various concentrations. Besides, there are results of calculating the volumetric characteristics of cement stone for water-cement relations used for cementing liquid radioactive waste. The review includes the results based on the development and implementation of solidification technologies for liquid radioactive waste using contact-hardening binders that form a durable waterproof stone at the time of pressing and do not require additional water for curing. Generated compounds for immobilization of liquid radioactive waste from nuclear power plants are tested to identify their strength characteristics, resistance to irradiation and leaching parameters. The paper covers the calculation of the cost of components for the solidification of liquid radioactive waste of various concentrations. The developed technology of liquid radioactive waste solidification allows obtaining compounds with strength up to 40 MPa. The volume of the final product is increased by 1.8 times, and the leaching rate is in the range of 1.10×10–4…9.5×10–5 kg/m2 per day.


Author(s):  
John D. Rubio

The degradation of steam generator tubing at nuclear power plants has become an important problem for the electric utilities generating nuclear power. The material used for the tubing, Inconel 600, has been found to be succeptible to intergranular attack (IGA). IGA is the selective dissolution of material along its grain boundaries. The author believes that the sensitivity of Inconel 600 to IGA can be minimized by homogenizing the near-surface region using ion implantation. The collisions between the implanted ions and the atoms in the grain boundary region would displace the atoms and thus effectively smear the grain boundary.To determine the validity of this hypothesis, an Inconel 600 sample was implanted with 100kV N2+ ions to a dose of 1x1016 ions/cm2 and electrolytically etched in a 5% Nital solution at 5V for 20 seconds. The etched sample was then examined using a JEOL JSM25S scanning electron microscope.


Author(s):  
Marjorie B. Bauman ◽  
Richard F. Pain ◽  
Harold P. Van Cott ◽  
Margery K. Davidson

2010 ◽  
pp. 50-56 ◽  
Author(s):  
Pablo T. León ◽  
Loreto Cuesta ◽  
Eduardo Serra ◽  
Luis Yagüe

2020 ◽  
Vol 39 (5) ◽  
pp. 6339-6350
Author(s):  
Esra Çakır ◽  
Ziya Ulukan

Due to the increase in energy demand, many countries suffer from energy poverty because of insufficient and expensive energy supply. Plans to use alternative power like nuclear power for electricity generation are being revived among developing countries. Decisions for installation of power plants need to be based on careful assessment of future energy supply and demand, economic and financial implications and requirements for technology transfer. Since the problem involves many vague parameters, a fuzzy model should be an appropriate approach for dealing with this problem. This study develops a Fuzzy Multi-Objective Linear Programming (FMOLP) model for solving the nuclear power plant installation problem in fuzzy environment. FMOLP approach is recommended for cases where the objective functions are imprecise and can only be stated within a certain threshold level. The proposed model attempts to minimize total duration time, total cost and maximize the total crash time of the installation project. By using FMOLP, the weighted additive technique can also be applied in order to transform the model into Fuzzy Multiple Weighted-Objective Linear Programming (FMWOLP) to control the objective values such that all decision makers target on each criterion can be met. The optimum solution with the achievement level for both of the models (FMOLP and FMWOLP) are compared with each other. FMWOLP results in better performance as the overall degree of satisfaction depends on the weight given to the objective functions. A numerical example demonstrates the feasibility of applying the proposed models to nuclear power plant installation problem.


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