Nonlinear Density Fluctuations and Spatial Heterogeneities near the Colloidal Glass Transition

2002 ◽  
Vol 754 ◽  
Author(s):  
Michio Tokuyama ◽  
Yayoi Terada ◽  
I. Oppenheima

ABSTRACTHow the spatial heterogeneities play an important role in the dynamics of density fluctuations near the colloidal glass transition is discussed from a new viewpoint. A nonlinear stochastic diffusion equation for the density fluctuations recently proposed by one of the present authors (MT) is numerically solved in two different initial states, an equilibrium state and a nonequilibrium state. Depending on initial states, the dynamics of the spatial heterogeneities are shown to be quite different from each other. Such differences are thus shown to influence the slow relaxations of density fluctuations, leading to different types of two-step relaxations.

2009 ◽  
Vol 106 (26) ◽  
pp. 10632-10637 ◽  
Author(s):  
E. H. Zhou ◽  
X. Trepat ◽  
C. Y. Park ◽  
G. Lenormand ◽  
M. N. Oliver ◽  
...  

Soft Matter ◽  
2014 ◽  
Vol 10 (27) ◽  
pp. 4822-4832 ◽  
Author(s):  
S. Fritschi ◽  
M. Fuchs ◽  
Th. Voigtmann

Soft glasses produced after the cessation of shear flow exhibit persistent residual stresses. Mode coupling theory of the glass transition explains their history dependence in terms of nonequilibrium, nonlinear-response relaxation of density fluctuations.


2021 ◽  
Vol 38 (10) ◽  
pp. 106101
Author(s):  
Xiaoyan Sun ◽  
Huaguang Wang ◽  
Hao Feng ◽  
Zexin Zhang ◽  
Yuqiang Ma

Identification of the glass formation process in various conditions is of importance for fundamental understanding of the mechanism of glass transitions as well as for developments and applications of glassy materials. We investigate the role of pinning in driving the transformation of crystal into glass in two-dimensional colloidal suspensions of monodisperse microspheres. The pinning is produced by immobilizing a fraction of microspheres on the substrate of sample cells where the mobile microspheres sediment. Structurally, the crystal-hexatic-glass transition occurs with increasing the number fraction of pinning ρ pinning, and the orientational correlation exhibits a change from quasi-long-range to short-range order at ρ pinning = 0.02. Interestingly, the dynamics shows a non-monotonic change with increasing the fraction of pinning. This is due to the competition between the disorder that enhances the dynamics and the pinning that hinders the particle motions. Our work highlights the important role of the pinning on the colloidal glass transition, which not only provides a new strategy to prevent crystallization forming glass, but also is helpful for understanding of the vitrification in colloidal systems.


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