scholarly journals Cation exchange capacity of an oxisol amended with an effluent from domestic sewage treatment

2005 ◽  
Vol 62 (6) ◽  
pp. 552-558 ◽  
Author(s):  
Adriel Ferreira da Fonseca ◽  
Luís Reynaldo Ferracciú Alleoni ◽  
Adolpho José Melfi ◽  
Célia Regina Montes
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Sewage Treatment ◽  
Barium Chloride ◽  
Dry Weight ◽  
Tropical Soils ◽  
Exchange Capacity ◽  
Strong Positive Correlation ◽  
Ionic Force ◽  
Barium Chloride Solution

The addition of Na-rich anthropogenic residues to tropical soils has stimulated the scientific community to study the role of sodium in both the soil solution and the exchange complex. In this study, several different methods were used to calculate the concentration of exchangeable and soluble cations and this data was then used to establish correlations between the level of these cations and both the accumulation of various elements and the dry weight of maize grown in a greenhouse under different conditions. In the closed environments of the pots, the most suitable method for calculating the effective cation exchange capacity (ECEC) was the cation exchange capacity calculated by cations removed with barium chloride solution (CEC S). Then again, the actual cation exchange capacity (CEC A) should be measured by using Mg adsorption to prevent ionic force from influencing electric charges. A strong positive correlation was obtained between the concentrations of Na in the 1:2 soil:water extracts and the accumulation of Na in the maize plants, indicating saline or double acid extractors are not needed when monitoring the Na concentration only.

A proposed method for the measurement of exchange properties of highly weathered soils

Soil Research ◽  
1979 ◽  
Vol 17 (1) ◽  
pp. 129 ◽  
Author(s):  
GP Gillman
Keyword(s):  
Ionic Strength ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Barium Chloride ◽  
Exchange Capacity ◽  
Potential Surfaces ◽  
Exchange Method ◽  
Barium Chloride Solution ◽  
Highly Weathered Soils ◽  
Basic Cations

The 'compulsive exchange' method of Bascomb has been modified to allow the determination of cation exchange capacity and anion exchange capacity of soils containing significant quantities of constant potential surfaces. The soil is equilibrated with unbuffered barium chloride solution at an ionic strength approximating that of the soil solution, so that the conditions under which determinations are made are similar to those found in the field. Barium on the exchange complex is then replaced by magnesium when the latter is added as magnesium sulfate, and this is accomplished without altering the solution ionic strength. If desired, exchangeable basic cations can be determined as an additional step in the procedure. Results obtained by the proposed method are compared with other commonly used procedures for determining cation exchange capacity and exchangeable basic cations.

scholarly journals Exchange Characteristics of Lead, Zinc, and Cadmium in Selected Tropical Soils

2014 ◽  
Vol 2014 ◽  
pp. 1-7
Author(s):  
Tope O. Bolanle-Ojo ◽  
Abiodun D. Joshua ◽  
Opeyemi A. Agbo-Adediran ◽  
Ademola S. Ogundana ◽  
Kayode A. Aiyeyika ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Tropical Soils ◽  
Exchange Capacity ◽  
Exchange Reactions ◽  
Soil System ◽  
Soil Systems ◽  
Wide Range ◽  
Lead Zinc ◽  
High Base

Conducting binary-exchange experiments is a common way to identify cationic preferences of exchangeable phases in soil. Cation exchange reactions and thermodynamic studies of Pb2+/Ca2+, Cd2+/Ca2+, and Zn2+/Ca2+were carried out on three surface (0–30 cm) soil samples from Adamawa and Niger States in Nigeria using the batch method. The physicochemical properties studies of the soils showed that the soils have neutral pH values, low organic matter contents, low exchangeable bases, and low effective cation exchange capacity (mean: 3.27 cmolc kg−1) but relatively high base saturations (≫50%) with an average of 75.9%. The amount of cations sorbed in all cases did not exceed the soils cation exchange capacity (CEC) values, except for Pb sorption in the entisol-AD2 and alfisol-AD3, where the CEC were exceeded at high Pb loading. Calculated selectivity coefficients were greater than unity across a wide range of exchanger phase composition, indicating a preference for these cations over Ca2+. TheKeqvalues obtained in this work were all positive, indicating that the exchange reactions were favoured and equally feasible. These values indicated that the Ca/soil systems were readily converted to the cation/soil system. The thermodynamic parameters calculated for the exchange of these cations were generally low, but values suggest spontaneous reactions.

Ion behavior in plant cell walls. II. Measurement of the Donnan free space, anion-exclusion space, anion-exchange capacity, and cation-exchange capacity in delignified Sphagnum russowii cell walls

1989 ◽  
Vol 67 (2) ◽  
pp. 460-465 ◽  
Author(s):  
Conrad Richter ◽  
Jack Dainty
Keyword(s):  
Cation Exchange ◽  
Anion Exchange ◽  
Free Space ◽  
Cell Walls ◽  
Cation Exchange Capacity ◽  
Dry Weight ◽  
Exchange Capacity ◽  
Anion Exchange Capacity ◽  
Anion Exclusion ◽  
Donnan Free Space

Isolated delignified cell walls from Sphagnum russowii Warnsdorf were incubated in various chloride salt solutions at neutral pH (pH 7 – 8), and ion sorption was measured directly by neutron activation analysis. The anion-exchange capacity was estimated to be 63 – 66 μequiv./g dry weight of wall material in the protonated form. The volume of the anion-exclusion space was 2.63 ± 0.21 (± SD, n = 3) and 1.65 ± 0.35 (± SD, n = 2) mL/g dry weight in NaCl and CaCl2, respectively. A novel approach to measure the Donnan free space is proposed: for walls equilibrated in a salt mixture containing 10 mequiv./L NaCl and 10 mequiv./L CaCl2, the Na+ ions can be considered "uncondensed" in the Manning sense. From the Donnan relationship for Na+ and Cl− ions in the internal and external phases, the Donnan free space was calculated to be 1.77 mL/g dry weight. Titrating walls from pH 2.1 to 9.1 in the presence of 10 mequiv./L NaCl and 10 mequiv./L CaCl2 revealed a maximum cation-exchange capacity above pH 6 of ca. 1900 μequiv./g dry weight. This corresponds to a fixed anionic charge concentration in the Donnan free space of 1.1 M. Key words: ion exchange, cell wall, Donnan free space.

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