scholarly journals Chemometry use in the evaluation of the sanya bay water quality

2010 ◽  
Vol 58 (4) ◽  
pp. 339-352 ◽  
Author(s):  
Jun-De Dong ◽  
Yan-Ying Zhang ◽  
You Shao Wang ◽  
Mei-Lin Wu ◽  
Si Zhang ◽  
...  

In this study, chemometric method is employed to identify anthropogenic effects on the water quality in Sanya Bay, South China Sea, and its marine and natural characteristics. Principal component analysis has extracted the four latent factors, thus explaining 85.52% of the total variance. Cluster analysis and principal component analysis have identified three different patterns of water quality based on anthropogenic effects and marine characteristics: Cluster I located in the outer and middle parts of the bay, Cluster II close to downtown Sanya, Cluster III located in the Sanya River estuary. In terms of the temporal pattern, principal component analysis and cluster analysis have distinguished the dry season from November to the following April, and the rainy season from May to October. The temporal pattern is related to climate and natural characteristics. The similarity index between variables and scores of samples can further distinguish the contribution of the variables to the samples. Both the polluting sources external to the Sanya River and the water from the South China Sea exercise an important influence on the water quality in Sanya Bay. These results may be valuable for socioeconomic development and human health in the Sanya Bay area.

2016 ◽  
Vol 2 (4) ◽  
pp. 211
Author(s):  
Girdhari Lal Chaurasia ◽  
Mahesh Kumar Gupta ◽  
Praveen Kumar Tandon

Water is an essential resource for all the organisms, plants and animals including the human beings. It is the backbone for agricultural and industrial sectors and all the small business units. Increase in human population and economic activities have tremendously increased the demand for large-scale suppliers of fresh water for various competing end users.The quality evaluation of water is represented in terms of physical, chemical and Biological parameters. A particular problem in the case of water quality monitoring is the complexity associated with analyzing the large number of measured variables. The data sets contain rich information about the behavior of the water resources. Multivariate statistical approaches allow deriving hidden information from the data sets about the possible influences of the environment on water quality. Classification, modeling and interpretation of monitored data are the most important steps in the assessment of water quality. The application of different multivariate statistical techniques, such as cluster analysis (CA), principal component analysis (PCA) and factor analysis (FA) help to identify important components or factors accounting for most of the variances of a system. In the present study water samples were analyzed for various physicochemical analyses by different methods following the standards of APHA, BIS and WHO and were subjected to further statistical analysis viz. the cluster analysis to understand the similarity and differences among the various sampling stations.  Three clusters were found. Cluster 1 was marked with 3 sampling locations 1, 3 & 5; Cluster-2 was marked with sampling location-2 and cluster-3 was marked with sampling location-4. Principal component analysis/factor analysis is a pattern reorganization technique which is used to assess the correlation between the observations in terms of different factors which are not observable. Observations correlated either positively or negatively, are likely to be affected by the same factors while the observations which are not correlated are influenced by different factors. In our study three factors explained 99.827% of variances. F1 marked  51.619% of total variances, high positive strong loading with TSS, TS, Temp, TDS, phosphate and moderate with electrical conductivity with loading values of 0.986, 0.970, 0.792, 0.744, 0.695,  0.701, respectively. Factor 2 marked 27.236% of the total variance with moderate positive loading with total alkalinity & temp. with loading values 0.723 & 0.606 respectively. It also explained the moderate negative loading with conductivity, TDS, and chloride with loading values -0.698, -0.690, -0.582. Factor F 3 marked 20.972 % of the variances with positive loading with PH, chloride, and phosphate with strong loading of pH 0.872 and moderate positive loading with chloride and phosphate with loading values 0.721, and 0.569 respectively. 


2011 ◽  
Vol 8 (4) ◽  
pp. 2000-2009 ◽  
Author(s):  
Hemant Pathak ◽  
S. N. Limaye

Groundwater is one of the major resources of the drinking water in Sagar city (India.). In this study 15 sampling station were selected for the investigations on 14 chemical parameters. The work was carried out during different months of the pre-monsoon, monsoon and post-monsoon seasons in June 2009 to June 2010. The multivariate statistics such as principal component and cluster analysis were applied to the datasets to investigate seasonal variations in groundwater quality. Principal axis factoring has been used to observe the mode of association of parameters and their interrelationships, for evaluating water quality. Average value of BOD, COD, ammonia and iron was high during entire study period. Elevated values of BOD and ammonia in monsoon, slightly more value of BOD in post-monsoon, BOD, ammonia and iron in pre-monsoon period reflected contribution on temporal effect on groundwater. Results of principal component analysis evinced that all the parameters equally and significantly contribute to groundwater quality variations. Factor 1 and factor 2 analysis revealed the DO value deteriorate due to organic load (BOD/Ammonia) in different seasons. Hierarchical cluster analysis grouped 15 stations into four clusters in monsoon, five clusters in post-monsoon and five clusters in pre-monsoon with similar water quality features. Clustered group at monsoon, post-monsoon and pre-monsoon consisted one station exhibiting significant spatial variation in physicochemical composition. The anthropogenic nitrogenous species, as fallout from modernization activities. The study indicated that the groundwater sufficiently well oxygenated and nutrient-rich in study places.


Author(s):  
Hyeuk Kim

Unsupervised learning in machine learning divides data into several groups. The observations in the same group have similar characteristics and the observations in the different groups have the different characteristics. In the paper, we classify data by partitioning around medoids which have some advantages over the k-means clustering. We apply it to baseball players in Korea Baseball League. We also apply the principal component analysis to data and draw the graph using two components for axis. We interpret the meaning of the clustering graphically through the procedure. The combination of the partitioning around medoids and the principal component analysis can be used to any other data and the approach makes us to figure out the characteristics easily.


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