WESTERN EXPLORERS AND VOLCANIC HEAT IN HAWAIʻI

2021 ◽  
Vol 40 (2) ◽  
pp. 607-624
Author(s):  
ALICE KIM ◽  
NICOLE C. LAUTZE

This paper is the first to compile the accounts of Western explorers to Hawai‘i who used volcanic heat. During the 1800s, Western explorers used volcanic heat when climbing and surveying Kīlauea and Mauna Loa volcanoes in Hawai‘i. The explorers cooked food on steam vents and lava streams. They drank condensed water from volcanic steam and bathed in a warm basin and warm springs. They warmed themselves near steam cracks and a lava stream, lit cigarettes with Kīlauea’s lava lake, and collected rocks. To confirm the presence of volcanic heat, this study uses geothermal resource maps and data from the Hawai‘i Play Fairway project. The areas where the explorers used volcanic heat have a probability of volcanic heat of 0.7 to 1.0, and elevated temperatures in nearby water wells indicate heat sources. Kīlauea and Mauna Loa erupted numerous times, and the surrounding areas experienced volcanic steam releases and lava flows. The explorers used volcanic heat to facilitate not only their survival but also the Western exploration and scientific investigation of Kīlauea and Mauna Loa volcanoes.

2020 ◽  
Vol 39 (1) ◽  
pp. 149-159
Author(s):  
ALICE KIM ◽  
NICOLE C. LAUTZE

This research serves as the first-known compilation of accounts of early Hawaiians using volcanic heat. Western explorers in the 1800s wrote about native Hawaiians near Kīlauea Volcano using volcanic heat for cooking and bathing. They cooked their food wrapped in leaves underground or above a steam crack at Sulphur Banks, Kīlauea Iki, and the Nāpau Crater Trail. Early Hawaiians bathed in the warm waters of Waiwelawela for health. To confirm the presence of volcanic heat, this study used geothermal resource maps by the Hawai‘i Play Fairway project. According to a probability map for volcanic heat, the areas where Hawaiians used volcanic heat have a probability of volcanic heat of 0.8 to 1.0. On a map with temperatures of water wells, water wells close to where Hawaiians used volcanic heat have elevated temperatures. Historically, the areas where Hawaiians used volcanic heat experienced volcanic steam release, volcanic eruptions, and lava flows.


2017 ◽  
Author(s):  
Emma L. Simpson ◽  
Paul J. Connolly ◽  
Gordon B. McFiggans

Abstract. The formation of ice in clouds can initiate precipitation and influence a cloud's reflectivity and lifetime, affecting climate to a highly uncertain degree. Nucleation of ice at elevated temperatures requires an ice nucleating particle (INP): so-called heterogeneous freezing. Previously reported measurements for the ability of a particle to nucleate ice have been made in the absence of other aerosol which will act as cloud condensation nuclei (CCN) and are ubiquitous in the atmosphere. Here we show that CCN can outcompete INPs for available water vapour thus suppressing ice formation, which has the potential to significantly affect the Earth's radiation budget. The magnitude of this suppression is shown to be dependent on the mass of condensed water required for freezing. Here we show that ice formation in a state-of-the-art cloud parcel model is strongly dependent on the criteria for heterogeneous freezing selected from those previously hypothesised. We have developed two alternative criteria which agree well with observations from cloud chamber experiments. This study highlights the dominant role that competition for water vapour can play in ice formation, highlighting both a need for clarity in the requirements for heterogeneous freezing and for measurements under atmospherically appropriate conditions.


2018 ◽  
Vol 18 (10) ◽  
pp. 7237-7250 ◽  
Author(s):  
Emma L. Simpson ◽  
Paul J. Connolly ◽  
Gordon McFiggans

Abstract. The formation of ice in clouds can initiate precipitation and influence a cloud's reflectivity and lifetime, affecting climate to a highly uncertain degree. Nucleation of ice at elevated temperatures requires an ice nucleating particle (INP), which results in so-called heterogeneous freezing. Previously reported measurements for the ability of a particle to nucleate ice have been made in the absence of other aerosol which will act as cloud condensation nuclei (CCN) and are ubiquitous in the atmosphere. Here we show that CCN can outcompete INPs for available water vapour thus suppressing ice formation, which has the potential to significantly affect the Earth's radiation budget. The magnitude of this suppression is shown to be dependent on the mass of condensed water required for freezing. Here we show that ice formation in a state-of-the-art cloud parcel model is strongly dependent on the criteria for heterogeneous freezing selected from those previously hypothesised. We have developed an alternative criteria which agrees well with observations from cloud chamber experiments. This study demonstrates the dominant role that competition for water vapour can play in ice formation, highlighting both a need for clarity in the requirements for heterogeneous freezing and for measurements under atmospherically appropriate conditions.


2021 ◽  
Author(s):  
Mayur Deshpande ◽  
Shamit Rathi ◽  
Sumit Songire ◽  
Ravikant Belakshe ◽  
John Davis

Abstract Southeast offshore India reservoirs have high-temperature deep water wells with significantly high pressures and unconsolidated sandstone formations. Controlling sand production is a major issue from inception to well completion and throughout the life of the well. A high density brine is required due to the high bottom hole pressures, thus executing sand control operations using such a high density brine as the base fluid for the gravel pack carrier fluid combined with the elevated temperatures is a significant challenge. A case is presented where a high-density temperature-resistant gravel packing fluid was optimized for a BHT of 320°F using a high-density brine. Additionally, the pH of the fluid was crucial considering the significant presence of CO2 in the formation, which was anticipated to affect asset integrity due to corrosion at low pH. A biopolymer-based fluid with oxidizing breaker was required in 14.2 ppg potassium-cesium formate brine and 12.5 ppg potassium formate brine. The fluid required evaluation for rheology and stability at 320°F, and at a shear rate of 170 s-1 with two conditions of viscosity to be sustained in the range of 75- 150 cP and 150-250 cP for the initial four-hour duration. The same fluid, after four hours, was also required to be broken within fourteen days. The fluid with the optimized formulation in regard with stability and rheology was further required to pass an acceptable sand suspension of ≤ 5% settling. Finally, the optimized fluid was required to show negligible corrosion effects on the downhole metallurgies. The stability and rheology were studied using a HPHT concentric cylinder viscometer. The sand suspension and corrosion characteristics were studied using an HPHT autoclave. The same fluid was studied with an acid breaker as a contingency for wells without CO2-related issues. After an extensive study, 12.72 gal/Mgal liquid gel concentrate of biopolymer when hydrated in 14.2 ppg and 15.45 gal/Mgal liquid gel concentrate of biopolymer, when hydrated in 12.5 ppg, providing viscosity in the range of 150-250 cP with 3 gal/Mgal and 5 gal/Mgal oxidizing breaker were selected, respectively. The optimized formulations passed sand suspension and had a pH in the range of 8-10, which imparted negligible corrosion loss to chrome- and nickel-based metallurgies. At the same conditions, the fluid showed acceptable results with 20 gal/Mgal organic acid breaker where the pH was ≤ 7. The combination of a commonly used biopolymer and a mixed formate brine produced a thermally stable fluid with unconventional chemistry, applicable for high-temperature, high-density conditions. With further study, it is expected that the temperature limit of this fluid can be extended beyond 320°F. The formulation for potassium formate brine was also tested at using field scale equipment to check for ease of mixing, reproducibility of results and for determining friction values when pumped at a certain rate via shunts. The fluid was mixed with relative ease using standard batch mixers and replicated the properties that were determined on a lab scale. The fluid also depicted superior proppant carrying capacities and lower friction numbers than expected which would enable lowering of overall surface pressures and surface pumping requirements.


Author(s):  
N. M. P. Low ◽  
L. E. Brosselard

There has been considerable interest over the past several years in materials capable of converting infrared radiation to visible light by means of sequential excitation in two or more steps. Several rare-earth trifluorides (LaF3, YF3, GdF3, and LuF3) containing a small amount of other trivalent rare-earth ions (Yb3+ and Er3+, or Ho3+, or Tm3+) have been found to exhibit such phenomenon. The methods of preparation of these rare-earth fluorides in the crystalline solid form generally involve a co-precipitation process and a subsequent solid state reaction at elevated temperatures. This investigation was undertaken to examine the morphological features of both the precipitated and the thermally treated fluoride powders by both transmission and scanning electron microscopy.Rare-earth oxides of stoichiometric composition were dissolved in nitric acid and the mixed rare-earth fluoride was then coprecipitated out as fine granules by the addition of excess hydrofluoric acid. The precipitated rare-earth fluorides were washed with water, separated from the aqueous solution, and oven-dried.


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