scholarly journals Preparation of Polythiophene Films Showing Optical Activity by Electrochemical Polymerisation in Cholesteric Liquid Crystal Containing Coumarine

Author(s):  
Hiroki Hayashi ◽  
Hiromasa Goto

We carried out electrochemical polymerisation in a cholesteric liquid crystal electrolyte solution. The polymer film prepared in the cholesteric liquid crystal showed chiropticality even though its monomer is an achiral. The surface morphology of the polymer was observed with polarising optical microscopy. Optical and electric properties were examined by UV-vis optical absorption, circular dichroism spectroscopy, and cyclic voltammetry.

Author(s):  
Hiroki Hayashi ◽  
Kohsuke Kawabata ◽  
Hiromasa Goto

We synthesised a rod like shaped new chiral inducer to construct chiral liquid crystal electrolyte solution. Next, electrochemical polymerisation was carried out in the chiral liquid crystal electrolyte solution. The surface morphology of the polymers were observed with polarising optical microscopy. Synthesis of the new chiral inducer and preparation of semi-conducting thin film in the cholesteric liquid crystal electrolyte solution were performed.


Author(s):  
Tomonori Ito ◽  
Tomoaki Jo ◽  
Jiuchao Dong ◽  
Hitoshi Hayashi ◽  
Hiromasa Goto

A ferroelectric liquid crystal was synthesised. We attempted electrochemical polymerisation in ferroelectric liquid crystal.


Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2430
Author(s):  
En-Lin Hsiang ◽  
Yannanqi Li ◽  
Ziqian He ◽  
Tao Zhan ◽  
Caicai Zhang ◽  
...  

Color-converted micro-light-emitting diode (micro-LED) displays with wide color gamut, high ambient contrast ratio, and fast response time are emerging as a potentially disruptive technology. However, due to limited optical density and thickness of the color-conversion film, the blue light leakage and low color-conversion efficiency still hinder their widespread applications. In this paper, we demonstrate a patterned cholesteric liquid crystal (CLC) polymer film with two special optical functionalities. On the green and red sub-pixels, the corresponding planar CLC texture acts as a distributed Bragg reflector for the blue light, which in turn improves the color conversion efficiency and expands the color gamut. On the blue sub-pixels, the corresponding focal-conic CLC texture acts as light scattering medium, which helps to reduce the angular color shift. Further analysis reveals that the patterned CLC film can alleviate the crosstalk between green and blue color filters. Therefore, compared to the display system without such a CLC film, our proposed device structure increases the color conversion efficiency by 143% (at ~90% Rec. 2020) and reduces average angular color shift Δu’v’ from 0.03 to 0.018 at the viewing angle with the most severe color shift. Such a patterned CLC film is applicable to all kinds of color-conversion display systems, including organic and inorganic phosphors.


2009 ◽  
Vol 29 (8) ◽  
pp. 794-798 ◽  
Author(s):  
V. I. Kolesnikov ◽  
S. F. Ermakov ◽  
A. P. Sychev ◽  
V. V. Mulyarchik

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