Novel Iron(II) and Copper(II) Polymeric Coordination Compounds with N,N′-bipyridine-type Ligands: Synthesis and Characterization

The paper presents the synthesis and characterization of Cu(II), Co(II), Ni(II), Cd(II), Zn(II) and Hg(II) complexes with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)-thiosemicarbazide. The new compounds were characterized by IR, EPR, electronic spectroscopy, magnetic moments, thermo-gravimetric analysis and elemental analysis.

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Synthesis and Characterization of New Oxovanadium(IV) Coordination Compounds with Pyrazol-5-one Azo Derivatives

Southern Brazilian Journal of Chemistry - Southern Brazilian Journal of Chemistry, Volume 28, No. 28, 2020 ◽

10.48141/sbjchem.v6.n7.1998.90_1998_2.pdf ◽

1998 ◽

Vol 6 (7) ◽

pp. 91-99

Author(s):

Anca EMANDI

Keyword(s):

Electronic Spectra ◽

Coordination Compounds ◽

Synthesis And Characterization ◽

Type I ◽

Molecular Weights ◽

Elementary Analysis ◽

Visible Spectra ◽

Azo Derivatives ◽

Donor System

A new series of oxovanadium(IV) chelates containing bi-and tridentate pyrazol-5-one azo derivatives ligands of the type (I) [VO(L)2] and (2) [VO(L)(H2O)] have been prepared and characterized by elementary analysis, IR, electronic spectra, conductance measurements, and molecular weights. The ligands coordinate through (O-N) donor system as monobasic and bidentate (HL) for the first type and through (0-N-O) donor system as dibasic and tridentate (H2L) for the second type of complexes. The molecular weights, the presence of the (V=O) stretching band around 950 cm -1, and the visible spectra suggest a monomeric penta-coordinated structure for these complexes.

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The synthesis of the heterocubane cluster [{CpMn}4(μ3-P)4] as a tetrahedral shaped starting material for the formation of polymeric coordination compounds

Chemical Communications ◽

10.1039/c5cc04800a ◽

2015 ◽

Vol 51 (70) ◽

pp. 13474-13477 ◽

Cited By ~ 5

Author(s):

Sebastian Heinl ◽

Konrad Kiefer ◽

Gábor Balázs ◽

Claudia Wickleder ◽

Manfred Scheer

Keyword(s):

Coordination Compounds ◽

Starting Material ◽

Phosphorus Containing ◽

High Yields ◽

Polymeric Coordination

Thermolysis of [CpMn(η6-cht)] with P4 in 1,3-diisopropylbenzene leads to the formation of the heterocubane [Cp4Mn4P4] (1) in high yields, as a rare example of ‘naked’ phosphorus containing complexes of manganese.

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Classical and ab initio preparation of reliable structures for polymeric coordination compounds

Comptes Rendus Chimie ◽

10.1016/j.crci.2006.06.007 ◽

2007 ◽

Vol 10 (1-2) ◽

pp. 82-88 ◽

Cited By ~ 3

Author(s):

Harald O. Jeschke ◽

L. Andrea Salguero ◽

Roser Valentí ◽

Christian Buchsbaum ◽

Martin U. Schmidt ◽

...

Keyword(s):

Ab Initio ◽

Coordination Compounds ◽

Polymeric Coordination

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Design, synthesis and characterization of copper-based coordination compounds with bidentate (N,N and N,O) ligands: reversible uptake of iodine, dye adsorption and assessment of their antibacterial properties

CrystEngComm ◽

10.1039/c8ce01348a ◽

2019 ◽

Vol 21 (2) ◽

pp. 251-262 ◽

Cited By ~ 10

Author(s):

Azizolla Beheshti ◽

Elham Sadat Mousavi Fard ◽

Maciej Kubicki ◽

Peter Mayer ◽

Carmel T. Abrahams ◽

...

Keyword(s):

Coordination Compounds ◽

Copper Complexes ◽

Antibacterial Properties ◽

Dye Adsorption ◽

Antibacterial Activities ◽

Synthesis And Characterization ◽

Design Synthesis ◽

Iodine Adsorption

This work presents the synthesis of close-packed copper complexes with an uncommon ability for dye and iodine adsorption and antibacterial activities.

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