Synthesis and Characterization of New Metal Complexes of &#945;-Aminonitriles Derived from P- Toluidine and Aromatic Aldehydes

New metal complexes of some transition metal ions Co(II), Cu(II) , Cd(II) and Zn(II) were prepared by their reaction with previously prepared ligands HLI= (P-methyl anilino) phenyl acetonitrile and HLII = (P-methyl anilino) –P– chloro phenyl acetonitrile . The two ligands were prepared by Strecker’s procedure which includ the reaction of p- toluidine with benzaldehyde and P- chlorobenzaldehyde respectively. Structures were proposed depending on atomic absorption , i.r. and u.v.visible spectra in addition to magnetic susceptibility and electrical conductivity measurements.

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Synthesis and Characterization of New Complexes of (N-P-Amino Diphenyl Amine) Amino (2-Hydroxy Phenyl) Acetonitrile Ligand with Some Transition Metal Ions

IOSR Journal of Applied Chemistry ◽

10.9790/5736-0320510 ◽

2013 ◽

Vol 3 (2) ◽

pp. 5-10 ◽

Cited By ~ 1

Author(s):

Ammar Jihad Alabdali

Keyword(s):

Transition Metal ◽

Metal Ions ◽

Transition Metal Ions ◽

Synthesis And Characterization ◽

Phenyl Acetonitrile ◽

Diphenyl Amine

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Synthesis and Characterization of a NewN"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)

E-Journal of Chemistry ◽

10.1155/2010/525197 ◽

2010 ◽

Vol 7 (2) ◽

pp. 409-418

Author(s):

Dilip C. Sawant ◽

A. Venkatchallam ◽

R. G. Deshmukh

Keyword(s):

Electrical Conductivity ◽

Metal Ions ◽

Metal Complexes ◽

Magnetic Measurements ◽

Divalent Metal ◽

Synthesis And Characterization ◽

Conductivity Measurements ◽

Divalent Metal Ions ◽

First Time

Synthesis and characterization of a newN"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its metal complexes with Co(II), Ni(II) and Cu(II) metal ions. The ligand synthesis and characterization is reported for first time. The complexes of divalent metal ions were synthesized in 1:2 molar proportion using ethanol as solvent. The ligands as well as its metal complexes were characterized using various physicochemical techniques such as elemental analysis, spectral and magnetic measurements and electrical conductivity measurements in case of the metal complexes only. The data for the metal complexes reveals that they may be represented by ML2. The metal complexes show interesting features of coordination structure.

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Synthesis and Characterization of Some Metal Complexes of [4-Methoxy-N-(pyrimidine-2-ylcarbamothioyl)benzamide]

Baghdad Science Journal ◽

10.21123/bsj.14.4.765-772 ◽

2017 ◽

Vol 14 (4) ◽

pp. 765-772

Author(s):

Baghdad Science Journal

Keyword(s):

Magnetic Susceptibility ◽

Metal Complexes ◽

Atomic Absorption ◽

Geometrical Structure ◽

Synthesis And Characterization ◽

Molecular Formula ◽

Conductivity Measurements ◽

Ft Ir ◽

Micro Analysis

A new ligand [4-Methoxy -N-(pyrimidine-2-ylcarbamothioyl) benzamide] (MPB) was synthesized by reactioniofi(4-Methoxyibenzoyliisothiocyanate)withi(2-aminopyri-midine). The Ligand was characterized by elemental micro analysis (C.H.N.S),(FT-IR) (UV- Vis) and (1Hi,13CNMR)spectra. Some transition metals complexes of this ligand were prepared and characterized by (FT-IR, UV-Vis) spectra conductivity measurements magnetic susceptibility and atomic absorption. From the obtained results the molecular formula of all complexes was suggested to be [M(MPB)2Cl2] (M+2i=Cu, Mn, Co ,Ni ,Zn ,Cd and Hg),the proposed geometrical structure for all complexes was an octahedral.

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