scholarly journals Distribution, source apportionment and health risk assessment of organochlorine pesticides in drinking groundwater

Author(s):  
John A. O. Oyekunle ◽  
Abiodun O. Adegunwa ◽  
Odunayo T. Ore

Abstract Groundwater samples of Ile-Ife, Osun State, Nigeria were investigated for their organochlorine pesticides (OCPs) levels. Probable sources of the OCPs and health risks associated with their consumption along with the water were determined in order to establish the potability of the groundwater samples. Quantitative determination of the OCPs was carried out by Gas Chromatography coupled with Electron Capture Detector (GC-ECD) after liquid-liquid extraction with dichloromethane (DCM). Results indicated that all the analyzed OCPs except p,p'-dichlorodiphenylethane were detected with high concentrations in the groundwater. Heptachlor (14.60±3.60 µg L-1) and methoxychlor (12.60±2.20 µg L-1) showed dominant concentrations that were higher than 0.02 ng L-1 maximum residue levels (MRLs) recommended by the European Union. Levels of the OCPs in the samples followed the decreasing trend: cyclodienes > diclorophehylethanes > chlorinated cyclohexanes, while the predominant source of the analyzed pesticides could be ascribed to aerial transportation from fresh applications in homes within the community. The carcinogenic health risk assessment also revealed consistent higher values of HQ and CR in children as opposed to adults, indicating that children are the more vulnerable population to the analyzed environmental contaminants.

2021 ◽  
Author(s):  
John A. O. Oyekunle ◽  
Abiodun O. Adegunwa ◽  
Odunayo T. Ore

Abstract Groundwater samples of Ile-Ife, Osun State, Nigeria were investigated for their organochlorine pesticides (OCPs) levels. Probable sources of the OCPs and health risks associated with their consumption along with the water were determined in order to establish the potability of the groundwater samples. Quantitative determination of the OCPs was carried out by Gas Chromatography coupled with Electron Capture Detector (GC-ECD) after liquid-liquid extraction with dichloromethane (DCM). Results indicated that all the analyzed OCPs except p,p'-dichlorodiphenylethane were detected with high concentrations in the groundwater. Heptachlor (14.60±3.60 µg L-1) and methoxychlor (12.60±2.20 µg L-1) showed dominant concentrations that were higher than 0.02 ng L-1 maximum residue levels (MRLs) recommended by the European Union. Levels of the OCPs in the samples followed the decreasing trend: cyclodienes > diclorophehylethanes > chlorinated cyclohexanes, while the predominant source of the analyzed pesticides could be ascribed to aerial transportation from fresh applications in homes within the community. The carcinogenic health risk assessment also revealed consistent higher values of HQ and CR in children as opposed to adults, indicating that children are the more vulnerable population to the analyzed environmental contaminants.


2021 ◽  
Author(s):  
John A. O. Oyekunle ◽  
Abiodun O. Adegunwa ◽  
Odunayo T. Ore

Abstract Groundwater samples of Ile-Ife, Osun State, Nigeria were investigated for their organochlorine pesticides (OCPs) levels. Probable sources of the OCPs and health risks associated with their consumption along with the water were determined in order to establish the potability of the groundwater samples. Quantitative determination of the OCPs was carried out by Gas Chromatography coupled with Electron Capture Detector (GC-ECD) after liquid-liquid extraction with dichloromethane (DCM). Results indicated that all the analyzed OCPs except p,p'-dichlorodiphenylethane were detected with high concentrations in the groundwater. Hepachlor (14.60±3.60 µg/L) and methoxychlor (12.60±2.20 µg/L) showed dominant concentrations that were higher than 0.02 ng/L maximum residue levels (MRLs) recommended by the European Union. Levels of the OCPs in the samples followed the decreasing trend: cyclodienes > diclorophehylethanes > chlorinated cyclohexanes, while the predominant source of the analyzed pesticides could be ascribed to aerial transportation from fresh applications in homes within the community. The carcinogenic health risk assessment also revealed consistent higher values of HQ and CR in children as opposed to adults, indicating that children are the more vulnerable population to the analyzed environmental contaminants.


2018 ◽  
Vol 07 (04) ◽  
pp. 143-152 ◽  
Author(s):  
Samuel Oluyemi Adefemi ◽  
Samuel Sunday Asaolu ◽  
Olayinka Abidemi Ibigbami ◽  
Joshua Iseoluwa Orege ◽  
Mayowa Akeem Azeez ◽  
...  

2020 ◽  
Vol 138 ◽  
pp. 111204
Author(s):  
Fadl Moussa ◽  
Samia Mokh ◽  
Samah Doumiati ◽  
Barbara Barboni ◽  
Nicola Bernabò ◽  
...  

2019 ◽  
Vol 82 ◽  
pp. 103238 ◽  
Author(s):  
Christophoros Christophoridis ◽  
Anna Kosma ◽  
Emmanouil Evgenakis ◽  
Anna Bourliva ◽  
Konstantinos Fytianos

Author(s):  
K. Nkitikpor ◽  
R. E. Jemerigbe

Aims: The health risk assessment of some toxic metals in groundwater in four selected towns of Delta State, Nigeria was confirmed by this study. Methodology: Ninety six groundwater samples were obtained from sixty four hand-dug wells and thirty two boreholes between December 2016 and May 2017. Samples were analyzed for heavy metals using standard procedures. Data collected was subjected to descriptive and inferential statistics using the Statistical Package for Social Sciences (SPSS) for Windows version 22.0. Health Risk Assessment for Non cancer hazard and carcinogenic effects were determined. Results: The HQ of Cr, Mn and Ni were below 1.0 indicating no threat to the water consumers while the HQ values for Pb, Cd and Cu were above 1.0 indicating risk to human health. The HI value was found to be greater than 1.0, indicating noncarcinogenic adverse effects. The estimated Lifetime of Carcinogenic Risks (LTCR) for Pb, Cr, Cd and Ni exceeded the predicted lifetime risk for carcinogens of 10−6 from ingestion pathway. The groundwater had higher risks of Cr and Cd as LTCR value in most sites were >10−4. The high LTCR should be given high priority as public health is concerned. Conclusions: This study indicated possible non-carcinogenic and carcinogenic human health hazard from groundwater consumption in study area through oral consumption.


Sign in / Sign up

Export Citation Format

Share Document