Bioremediation of artificially crude oil polluted soil of veritas University Abuja using poultry manure

The removal of hydrocarbon compounds from the environment has always been a difficult undertaking for people all over the world. As a result, remedial efforts are required to safeguard the environment as well as to restore agriculture. This study looked at how poultry manure (dung) could help in the bioremediation of Veritas University's intentionally crude oil polluted soil. The physical properties of the soil and total petroleum hydrocarbon content of the crude oil polluted soil were determined, followed by the isolation and identification of microorganisms present in the soil and poultry manure before and after pollution with crude oil. These analyses were done according to standard operating procedures. Within a six-month timeframe, the natural attenuation and poultry manure amendment option for remediating the crude oil-polluted soil were monitored and the residual hydrocarbon content of the polluted soil after remediation evaluated. There was an overall decrease in pH level during the experimental units containing 4 g amendment, 2 g amendment and the untreated polluted soil in the order 8.4 to 7.1, 8.4 to 7.2 and 8.1 to 6.7, respectively. Temperature was within 27oC and 31oC, the treated soil that contained 4 g dung had an initial moisture content of 58%, and 35% after remediation. The hydrocarbon utilizing bacteria isolated were Pseudomonas species, Staphylococcus species, and Bacillus species, while the hydrocarbon utilizing fungi isolated were Aspergillus niger, Fusarium solani and Candida albicans. There was more significant microbial increase in the sample containing 4 g poultry manure treatment than 2 g poultry manure treatment and natural attenuation. Total hydrocarbon quantity significantly decreased after six months with the complete removal of C4, C7, C19 and C37 from the treated sample containing 4 g poultry manure. This indicated that the negative effects of crude oil on the environment can be mitigated by adding poultry manure.

The influence of meteorological conditions during traditional smoking on polycyclic aromatic hydrocarbon content in traditional Polish pork ham

The aim of the study was to examine the influence of meteorological conditions observed during the process of traditional smoking on polycyclic aromatic hydrocarbon content in traditional Polish pork ham. The material of the study comprised traditional Polish pork ham, one of the most frequently purchased and consumed meat products in Poland. The analysed ham was smoked with the traditional method using beech chips and pieces. Smoking time was four hours. During laboratory research the basic chemical composition of the product was examined. Using the HPLC method, the level of 15 selected Polycyclic Aromatic Hydrocarbons (PAHs). The obtained results show that the level of selected polycyclic aromatic hydrocarbons in the examined material depended on atmospheric pressure and relative air humidity. Atmospheric pressure significantly influenced the content of benzo(b)fluoranthene, benzo(a)anthracene and indeno(c,d)pyrene. Relative humidity impacted the absorption level of 5-methylchrysene, benzo(a)pyrene, benzo(b)fluoranthene, benzo(g,h,i)perylene, benzo(j)fluoranthene and indeno(c,d)pyrene. An influence of air temperature during the smoking process on PAHs content in the product was not observed. The results indicate that traditional smoking should be conducted under conditions of high relative humidity – ideally above 75%, and high atmospheric pressure – above 1000 hPa.

Physicochemical properties, total hydrocarbon content, and trace metals of water and sediments from major River Estuaries within the Niger Delta Region of Nigeria

Water and sediment samples from Cross River, Imo River, and Qua Iboe River Estuaries were collected and treated using standard analytical procedures. The samples were analyzed for their physicochemical properties, total hydrocarbon content (THC), and trace metals. Results obtained revealed that, the mean levels of total suspended solids (TSS), total dissolved solids (TDS), turbidity, colour, biochemical oxygen demand (BOD), THC, cadmium (Cd), iron (Fe), nickel (Ni), lead (Pb), and zinc (Zn) in water were higher than their acceptable limits in Nigeria. Whereas, the mean levels water pH, electrical conductivity (EC), dissolved oxygen (DO), nitrate, sulphate, phosphate, and copper (Cu) were within their acceptable limits. The results obtained also revealed that, the mean levels of nitrate, THC, and Fe in sediments were higher than their recommended limits. While the levels of pH, EC, sulphate, phosphate, Cd, Cu, Ni, Pb, and Zn in sediments were within their recommended limits. This study indicated that the anthropogenic activities by oil and oil-related companies within the Niger Delta Region of Nigeria may have contributed significantly to the high level of toxic substances in the water channels within the zone. The results obtained revealed that, the direct or indirect exposure to untreated water from the studied water channels may result in serious health challenges. Hence, the environment should be closely monitored to forestall a devastating situation in the region.

Oil Pollution Analysis of Gjanica River from Petroleum Rafinery and Production Industry in Albania

Aim: Oil industry has its effect in environmental. For this reason we evaluated oil pollution from oil extraction processes, and petroleum refinery in Gjanica River. Study Design: Analysis of hydrocarbon content for river bed pollution from oil industry are evaluated. This is made by comparing gas chromatogram with the model. Place and Duration of the Study: University of Vlora and ex Oil and gas Institute Fier between August 2016 and March, 2017. Methodology: Sediment samples were collected in the Gjanica River. Extracts were prepared and taken using Soxhlet apparatus in ex Oil and Gas Institute in Fier. And hydrocarbons contents were evaluated using Hewlett Packard 5890 series II gas chromatography. Results: Based on the results of oxygen indicators in the Gjanica River COD = 559mg/l and BOD5 = 102.5 mg/l, we conclude that there are no living beings in this area. And based on six sediment samples analysed we see old and new hydrocarbon compounds in bed River. Conclusion: High levels of oil products discharges have damaged the living life of the river water for, more than fifty year. This quantity has contaminated sediments of the bed and/or river banks that need to be removed.

The structural transformation and reburning characteristics of gas coal in Ningwu coalfield fire

With the expansion of the scale of coal mining, the safety problems caused by the reburning of coal are becoming more and more serious. In this paper, the pyrolysis characteristics of gas coal and the exothermic characteristics of reoxidation of residues were studied by using a synchronous thermal analyzer. The functional groups of pyrolysis residues were tested, and the group content and characteristic structural parameters were calculated based on quantum chemistry method. The results show that with the increase of pyrolysis temperature, Volatile maximum separation rate (Vmax) and the change in the residual weight of the coal sample (ΔWvp) increase. The increase of temperature will lead to the decrease of hydroxyl and aliphatic hydrocarbon content in coal, and the increase of aromatic hydrocarbon. With the deepening of pyrolysis, the ignition point temperature of coal samples decreases first and then rises, the combustion intensity and combustion concentration are strengthened. The pyrolysis results show that 462.8°C is the critical temperature for the transition during pyrolysis. The ignition point of the residue is less affected by the pyrolysis conditions, and the ignition temperature of the raw coal and the pyrolysis residue varies within 330.57°C–334.98°C.

Quantitative Method for Evaluating Shale Oil Resources Based on Movable Oil Content

The light hydrocarbon content ( S 1 ) of shale oil is lost in aboveground experimental measurements, which do not accurately reflect actual underground light hydrocarbon content and cannot meet the demands of resource quantity calculation. Based on field and laboratory experimental data from the second member of the Kongdian Formation in the Cangdong Sag, Bohai Bay Basin, the retained oil and movable oil contents in shale were calculated using a mathematical formula, and the total resources were quantified. The correction coefficient of S 1 from pyrolysis and the adsorption of oil by the total organic carbon (TOC) were determined to be 1.25 and 100 mg/g, respectively. The calculated parameter movable oil content ( S movable ) and the corresponding calculation formula of S 1 are proposed. The lower limit of S 1 is 100 mg HC/g rock, the TOC content is 4 wt % and 6 wt %, and the corrected movable oil content of 3 mg/g and 6 mg/g, respectively, will be of great significance in shale oil geology and engineering. The optimal geological and engineering settings are divided into three categories and eight subcategories on the basis of these findings. Methods for evaluating total, movable, and recoverable oil resources from shale are discussed, which elucidate a new method for quantitative evaluation and ranking of shale oil resources. This approach is suitable for application in other shale oil exploration and development areas globally.

Assessment of the physicochemical qualities of groundwater and soils around oil-producing communities in Afam, area of Porthacourt, Niger Delta Nigeria

Results from the assessment of physicochemical qualities of groundwater and soils around Afam in Niger Delta done using, statistical model, geo-accumulation indices (I-geo) and water quality indices showed that pH and Cu did not correlate strongly with any of the parameters analyzed in the study area. At 2-tailed of 0.05 levels of significance, moderate correlation exist between dissolved oxygen and Ca > Na, strong to moderate correlation exist between temperature and total dissolved solids (TDS) > E.C > Na and Ca, whereas at 2-tailed level of 0.02, very strong correlation exist between E.C and TDS (0.988), > Na (0.966), > Ca (0.957). TDS in turn is strongly correlated with Na (0.987), > Ca (0.972). Fe, Zn, Pb and Cr, total petroleum hydrocarbon (TPHC), oil and grease (O&G) (< 0.001 mg/l) did not correlate with any of the physicochemical elements in the samples. At 2-tailed levels of 0.02 and 0.05, no significant correlation exists between alkalinity and salinity in groundwater samples and also with any the elements. Groundwater showed excellent water quality except one (62.307). pH, Cr, Fe, Ni, Pb and Cu in the soil were unpolluted since I-geo values are less than 1. Polycyclic aromatic hydrocarbon (PAH) (2.5194) showed low pollution, O&G (3.8886) showed moderate pollution, while total hydrocarbon content (THC) (6.2069), total organic carbon (TOC) (7.4919) and TPHC (9.4851) showed extreme pollution. The control site appeared to be unpolluted except TOC (6.8721). Percentage of clay particles in the soil is higher than in control.

Bioremediasi Tanah Terkontaminasi Hidrokarbon Menggunakan Teknik Bioaugmentasi

Among various bioremediation methods, bioaugmentation is the one which frequently used. In this study, bioaugmentation was conducted by utilising Pseudomonas aeruginosa, Bacillus cereus, and Brevibacterium flavum. Many studies on and implementations of this method have been conducted. However, this method still needed to be studied especially with reference to its implementations to small automotive workshops, which their number was increasing, as the sources of the soil contamination. The objective of this study was to identify the most effective bacteria in removing total hydrocarbon content (TPH) from contaminated soils and to understanding several characteristics of the method. Laboratory research was set up and the experimental design was complete randomised design (CRD) with three replications. Statistical test of Anova with α 5% was carried out to evaluate the results of the study. The treatments of this study were three species of bacteria which were inoculated separately into the contaminated soils. The parameters were TPH, pH and the density of bacteria consortiums. The highest effective removal of TPH was showed by P. aeruginosa, 64,1% (δ+2,61%), followed by B. flavum and B cereus. This treatment had pH dropped two points and the density of bacteria consortium increased 6-10 times. The main limitation of this study was the number of parameters which was a few resulting difficulties in understanding the hydrocarbon degradation processes. The results of this study may give significant contributions to managers of small automotive workshops in cities which currently are not managed their spills properly.

Stimulating the Rate of Phytoremediation of Chromolaena odorata in Crude Oil Contaminated Soil Using Inorganic Urea

Investigation on the use of urea in stimulating the phytoremediation of Chromolaena odorata in a crude oil contaminated soil was carried out at a crude oil spilled site at Botem-Tai, Ogoni, Nigeria. Three phytoremediation treatments labeled A – C in addition to the control (D) were used. The treatments were: A (Chromolaena odorata only), B (Chromolaena odorata + 20 g/m2 urea), C (Chromolaena odorata + 40 g/m2 urea), D (polluted soil without phytoremediation) arranged using Latin Square Design (LSD). Total petroleum hydrocarbon (TPH) and Total hydrocarbon content (THC) in soil and plant samples from the different treatment plots in addition to other soil nutrients were analyzed. The percentage reduction in TPH and THC in soil were as follows: Treatment B, {TPH (92.08%) and THC (95.37%)} > treatment A {TPH (88.95%) and THC (93.37%)}> C {TPH (78.78%) and THC (83.29%)} > Control {TPH (14.76%) and THC (32.90%)}. Treatment C had the highest TPH (2.67 mg/kg) and THC (20.57 mg/kg) accumulation in test plant. Combining stimulant (urea) with phytoremediation also improved soil properties such as pH, Nitrogen and Potassium. With the highest reduction of TPH and THC in treatment B (phytoremediation with 20 g/m2 urea) than other treatments is an indication that low concentration of urea has a stimulatory effect on phytoremediation of crude oil by Chromolaena odorata.