scholarly journals Numerical Study of Plasmonic Effects of Ag Nanoparticles embedded in the Active Layer on performance polymer organic Solar Cells

2021 ◽  
Author(s):  
Leila Shabani ◽  
ahmad mohammadi ◽  
Tahmineh Jalali
Keyword(s):  
Solar Cells ◽  
Optical Absorption ◽  
Active Layer ◽  
Light Absorption ◽  
Numerical Study ◽  
Short Circuit ◽  
Hexagonal Lattice ◽  
Three Dimensional ◽  
Plasmonic Nanoparticles ◽  
Core Shell

Abstract In this paper, the light absorption the active layer of polymer polymer solar cells (OPV) by using plasmonic nanocrystals with hexagonal lattice is investigated. To study the relation between the performance of the OPV solar cell and its active layer, a three-dimensional model for its morphology is utilized. Therefore, the three-dimensional (3D) finite-difference time-domain method and Lumirical software were used to measure the field distribution and light absorption in the active layer in terms of wavelength. OPV solar cells with bilayer and bulk heterojunction structured cells were designed using hexagonal lattice crystals with plasmonic nanoparticles, as well as, core-shell geometry to govern a design to optimize light trapping in the active layer. The parameters of shape, material, periodicity, size, the thickness of the active layer as a function of wavelength in OPV solar cells have been investigated. A very thin active layer and an ultra-thin shell were used to achieve the highest increase in optical absorption. The strong alternating electromagnetic field around the core-shell plasmonic nanoparticles resulting from the localized surface plasmon resonance (LSPR) suggested by the Ag plasmonic nanocrystals increased the intrinsic optical absorption in the active layer poly(3-hexylthiophene):phenyl-C61-butyric acid methyl ester (P3HT:PCBM). Based on the photovoltaic results the short circuit current ranged from 19.7 to 26.7 mA/cm2.PACs Number: 88.40.hj, 88.40.jj, 42.70.Qs

Improving light absorption of active layer by adjusting PEDOT:PSS film for high efficiency Si-based hybrid solar cells

Solar Energy ◽  
2021 ◽  
Vol 228 ◽  
pp. 299-307
Author(s):  
Zhongliang Gao ◽  
Ting Gao ◽  
Qi Geng ◽  
Guilu Lin ◽  
Yingfeng Li ◽  
...  
Keyword(s):  
Solar Cells ◽  
Active Layer ◽  
Light Absorption ◽  
High Efficiency ◽  
Hybrid Solar Cells

scholarly journals Direct AFM-based nanoscale mapping and tomography of open-circuit voltages for photovoltaics

2018 ◽  
Vol 9 ◽  
pp. 1802-1808 ◽  
Author(s):  
Katherine Atamanuk ◽  
Justin Luria ◽  
Bryan D Huey
Keyword(s):  
Solar Cells ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Photovoltaic Performance ◽  
Three Dimensional ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Photovoltaic Properties ◽  
Order Of Magnitude ◽  
Individual Grains

The nanoscale optoelectronic properties of materials can be especially important for polycrystalline photovoltaics including many sensor and solar cell designs. For thin film solar cells such as CdTe, the open-circuit voltage and short-circuit current are especially critical performance indicators, often varying between and even within individual grains. A new method for directly mapping the open-circuit voltage leverages photo-conducting AFM, along with an additional proportional-integral-derivative feedback loop configured to maintain open-circuit conditions while scanning. Alternating with short-circuit current mapping efficiently provides complementary insight into the highly microstructurally sensitive local and ensemble photovoltaic performance. Furthermore, direct open-circuit voltage mapping is compatible with tomographic AFM, which additionally leverages gradual nanoscale milling by the AFM probe essentially for serial sectioning. The two-dimensional and three-dimensional results for CdTe solar cells during in situ illumination reveal local to mesoscale contributions to PV performance based on the order of magnitude variations in photovoltaic properties with distinct grains, at grain boundaries, and for sub-granular planar defects.

scholarly journals Enhancing the Photovoltaic Performance of Perovskite Solar Cells Using Plasmonic Au@Pt@Au Core-Shell Nanoparticles

Nanomaterials ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1263 ◽  
Author(s):  
Bao Wang ◽  
Xiangyu Zhu ◽  
Shuhan Li ◽  
Mengwei Chen ◽  
Nan Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Chemical Reduction ◽  
Short Circuit ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Open Circuit ◽  
Core Shell ◽  
Shell Nanoparticles ◽  
Local Surface Plasmon Resonance ◽  
Core Shell Nanoparticles

Au@Pt@Au core-shell nanoparticles, synthesized through chemical reduction, are utilized to improve the photoelectric performance of perovskite solar cells (PSCs) in which carbon films are used as the counter electrode, and the hole-transporting layer is not used. After a series of experiments, these Au@Pt@Au core-shell nanoparticles are optimized and demonstrate outstanding optical and electrical properties due to their local surface plasmon resonance and scattering effects. PSC devices containing 1 wt.% Au@Pt@Au core-shell nanoparticles have the highest efficiency; this is attributable to their significant light trapping and utilization capabilities, which are the result of the distinctive structure of the nanoparticles. The power conversion efficiency of PSCs, with an optimal content of plasmonic nanoparticles (1 wt.%), increased 8.1%, compared to normal PSCs, which was from 12.4% to 13.4%; their short-circuit current density also increased by 5.4%, from 20.5 mA·cm−2 to 21.6 mA·cm−2. The open-circuit voltages remaining are essentially unchanged. When the number of Au@Pt@Au core-shell nanoparticles in the mesoporous TiO2 layer increases, the photovoltaic parameters of the former shows a downward trend due to the recombination of electrons and holes, as well as the decrease in electron transporting pathways.

A wrinkled structure with broadband and omnidirectional light-trapping abilities for improving the performance of organic solar cells with low defect density

Nanoscale ◽  
2019 ◽  
Vol 11 (46) ◽  
pp. 22467-22474 ◽  
Author(s):  
Kong Liu ◽  
Yang Sun ◽  
Qicong Li ◽  
Cheng Yang ◽  
Muhammad Azam ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Transport ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Light Absorption ◽  
Defect Density ◽  
Light Trapping ◽  
Transport Efficiency ◽  
Wrinkled Structure

A wrinkled structure could enhance omnidirectional light absorption in the organic active layer and charge transport efficiency at the interface.

Numerical study on the short-circuit current in single layer organic solar cells with Schottkey contacts

2010 ◽  
Vol 6 (2) ◽  
pp. 103-107
Author(s):  
Chao-zhu Ma ◽  
Wei-min Meng ◽  
Ying-quan Peng ◽  
Run-sheng Wang ◽  
Rong-hua Li ◽  
...  
Keyword(s):  
Solar Cells ◽  
Organic Solar Cells ◽  
Numerical Study ◽  
Short Circuit ◽  
Single Layer ◽  
Short Circuit Current

Photonic Crystal Back Reflectors for Enhanced Absorption in Amorphous Silicon Solar Cells

2010 ◽  
Vol 1245 ◽  
Author(s):  
Benjamin Curtin ◽  
Rana Biswas ◽  
Vikram Dalal
Keyword(s):  
Solar Cells ◽  
Photonic Crystal ◽  
Amorphous Silicon ◽  
Light Absorption ◽  
Short Circuit ◽  
Silicon Solar Cells ◽  
Etch Depth ◽  
Enhanced Absorption ◽  
Back Reflectors ◽  
Back Reflector

AbstractPhotonic crystal back reflectors offer enhanced optical absorption in thin-film solar cells, without undesirable losses. Rigorous simulations of photonic crystal back reflectors predicted maximized light absorption in amorphous silicon solar cells for a pitch of 700-800 nm. Simulations also predict that for typical 250 nm i-layer cells, the periodic photonic crystal back reflector can improve absorption over the ideal randomly roughened back reflector (or the ‘4n2classical limit') at wavelengths near the band edge. The PC back reflector provides even higher enhancement than roughened back reflectors for cells with even thinner i-layers. Using these simulated designs, we fabricated metallic photonic crystal back reflectors with different etch depths and i-layer thicknesses. The photonic crystals had a pitch of 760 nm and triangular lattice symmetry. The average light absorption increased with the PC back reflectors, but the greatest improvement (7-8%) in short circuit current was found for thinner i-layers. We have studied the dependence of cell performance on the etch depth of the photonic crystal. The photonic crystal back reflector strongly diffracts light and increases optical path lengths of solar photons.

Fabrication of Core-Shell Structured TiO2/MgO Electrodes for Dye-Sensitized Solar Cells

2015 ◽  
Vol 787 ◽  
pp. 3-7 ◽  
Author(s):  
S. Karuppuchamy ◽  
C. Brundha
Keyword(s):  
Solar Cells ◽  
Short Circuit ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Core Shell ◽  
Dye Sensitized ◽  
The Core ◽  
Sensitized Solar Cells

We demonstrated the construction and performance of dye-sensitized solar cells (DSCs) based on nanoparticles of TiO2coated with thin shells of MgO by simple solution growth technique. The XRD patterns confirm the presence of both TiO2and MgO in the core-shell structure. The effect of varied shell thickness on the photovoltaic performance of the core-shell structured electrode is also investigated. We found that MgO shells of all thicknesses perform as barriers that improve open-circuit voltage (Voc) of the DSCs only at the expense of a larger decrease in short-circuit current density (Jsc). The energy conversion efficiency was greatly dependent on the thickness of MgO on TiO2film, and the highest efficiency of 4.1% was achieved at the optimum MgO shell layer.

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