Toward an Atomic Level Understanding of Heterogeneous Reaction Rate Enhancement Employing Gas Phase Metal and Metal Oxide Clusters

2010 ◽  
Author(s):  
Elliot R. Bernstein
Keyword(s):  
Metal Oxide ◽  
Gas Phase ◽  
Reaction Rate ◽  
Heterogeneous Reaction ◽  
Atomic Level ◽  
Rate Enhancement ◽  
Metal Oxide Clusters

Catalytic CO Oxidation by Gas-Phase Metal Oxide Clusters

2019 ◽  
Vol 123 (43) ◽  
pp. 9257-9267 ◽  
Author(s):  
Xiao-Na Li ◽  
Li-Na Wang ◽  
Li-Hui Mou ◽  
Sheng-Gui He
Keyword(s):  
Metal Oxide ◽  
Co Oxidation ◽  
Gas Phase ◽  
Catalytic Co Oxidation ◽  
Metal Oxide Clusters

scholarly journals Structural variability in transition metal oxide clusters: gas phase vibrational spectroscopy of V3O6–8+

2012 ◽  
Vol 14 (26) ◽  
pp. 9377 ◽  
Author(s):  
Knut R. Asmis ◽  
Torsten Wende ◽  
Mathias Brümmer ◽  
Oliver Gause ◽  
Gabriele Santambrogio ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxide ◽  
Gas Phase ◽  
Vibrational Spectroscopy ◽  
Transition Metal Oxide ◽  
Metal Oxide Clusters ◽  
Structural Variability ◽  
Transition Metal Oxide Clusters

Probing Ionic Association on Metal Oxide Clusters by Pulsed Field Gradient NMR Spectroscopy: The Example of Sn12–Oxo Clusters

2004 ◽  
Vol 10 (7) ◽  
pp. 1747-1751 ◽  
Author(s):  
François Ribot ◽  
Virginie Escax ◽  
José C. Martins ◽  
Monique Biesemans ◽  
Laurent Ghys ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Metal Oxide ◽  
Field Gradient ◽  
Ionic Association ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Metal Oxide Clusters

Magnetic properties of metal oxide clusters linked by flexible chain siloxane fragments

1999 ◽  
Vol 48 (9) ◽  
pp. 1670-1672
Author(s):  
M. M. Levitsky ◽  
A. R. Arutyunyan ◽  
B. G. Zavin ◽  
V. V. Erokhin ◽  
A. L. Buchachenko
Keyword(s):  
Magnetic Properties ◽  
Metal Oxide ◽  
Flexible Chain ◽  
Metal Oxide Clusters

Ab Initio Computation of Thermochemistry and Kinetics in the Oxidation of Gas Phase Silicon Species

1992 ◽  
Vol 282 ◽  
Author(s):  
Michael R. Zachariah ◽  
Wing Tsang
Keyword(s):  
Ab Initio ◽  
Gas Phase ◽  
Energy Barrier ◽  
Reaction Rate ◽  
Rate Theory ◽  
Molecular Orbital Calculations ◽  
Activation Energy Barrier ◽  
Ab Initio Computation ◽  
Oxygen Donor ◽  
Reaction Rate Theory

ABSTRACTAb initio molecular orbital calculations coupled to RRKM reaction rate theory have been conducted on some important reactions involved in the oxidation of silane in a high-temperature/high H2O environment. The results indicate thatH2O acts as an oxygen donor to SiH2 to form H3SiOH or SiH2O. Subsequent reactions involve the formation of (HSiOOH, H2Si(OH)2,:Si(OH)2 or SiO). In turn SiO polymerizes into planar rings, without an activation energy barrier. A list of calculated thermochemical data are also presented for a number of equilibrium species.

Sign in / Sign up

Export Citation Format

Share Document