A Single Solvating Benzene Molecule Decouples the Mixed-Valence Complex Through Intermolecular Orbital Interactions

SSRN Electronic Journal ◽

10.2139/ssrn.3996402 ◽

2021 ◽

Author(s):

Suman Mallick ◽

Miao Meng ◽

Xiaoli Chen ◽

Ying Ning Tan ◽

Yuli Zhou ◽

...

Keyword(s):

Mixed Valence ◽

Benzene Molecule ◽

Orbital Interactions ◽

Mixed Valence Complex

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The influence of cis/trans isomerism on the physical properties of a cyano-bridged dinuclear mixed valence complex

Journal of the Chemical Society Dalton Transactions ◽

10.1039/b110461f ◽

2002 ◽

pp. 1435 ◽

Cited By ~ 30

Author(s):

Paul V. Bernhardt ◽

Brendan P. Macpherson ◽

Manuel Martinez

Keyword(s):

Physical Properties ◽

Mixed Valence ◽

Mixed Valence Complex

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Design, synthesis and physico-chemical studies of a Co(II)/Co(III) mixed-valence complex: An experimental and DFT approach.

Journal of Molecular Structure ◽

10.1016/j.molstruc.2021.130384 ◽

2021 ◽

pp. 130384

Author(s):

Intissar Hamdi ◽

Noureddine Mhadhbi ◽

Noureddine Issaoui ◽

Andreas Roodt ◽

Mark M. Turnbull ◽

...

Keyword(s):

Mixed Valence ◽

Design Synthesis ◽

Physico Chemical ◽

Chemical Studies ◽

Mixed Valence Complex

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ChemInform Abstract: EXPERIMENTAL EVIDENCE FOR TRAPPED VALENCES IN THE MIXED-VALENCE COMPLEX μ-PYRAZINE-BIS(PENTAAMMINERUTHENIUM) TOSYLATE. ELECTRON PARAMAGNETIC RESONANCE, MAGNETIC SUSCEPTIBILITY, AND NUCLEAR MAGNETIC RESONANCE RESULTS

Chemischer Informationsdienst ◽

10.1002/chin.197838290 ◽

1978 ◽

Vol 9 (38) ◽

Author(s):

B. C. BUNKER ◽

R. S. DRAGO ◽

D. N. HENDRICKSON ◽

R. M. RICHMAN ◽

S. L. KESSELL

Keyword(s):

Nuclear Magnetic Resonance ◽

Electron Paramagnetic Resonance ◽

Magnetic Susceptibility ◽

Magnetic Resonance ◽

Experimental Evidence ◽

Mixed Valence ◽

Paramagnetic Resonance ◽

Electron Paramagnetic ◽

Mixed Valence Complex ◽

Nuclear Magnetic

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Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp(dppe)Fe-C4-FeCp(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)

Journal of the American Chemical Society ◽

10.1021/ja00132a013 ◽

1995 ◽

Vol 117 (27) ◽

pp. 7129-7138 ◽

Cited By ~ 262

Author(s):

Nathalie Le Narvor ◽

Loic Toupet ◽

Claude Lapinte

Keyword(s):

Crystal Structure ◽

Elemental Carbon ◽

Mixed Valence ◽

Spectroscopic Properties ◽

Carbon Chain ◽

X Ray ◽

Mixed Valence Complex

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Class III Delocalization in a Cyanide-Bridged Trimetallic Mixed-Valence Complex

Angewandte Chemie ◽

10.1002/ange.201307025 ◽

2013 ◽

Vol 126 (5) ◽

pp. 1317-1320 ◽

Cited By ~ 12

Author(s):

German E. Pieslinger ◽

Pablo Alborés ◽

Leonardo D. Slep ◽

Luis M. Baraldo

Keyword(s):

Mixed Valence ◽

Class Iii ◽

Mixed Valence Complex

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Structure of a one-dimensional Br-bridged PtII-PtIV mixed-valence complex, catena-poly[bis(ethylenediamine)platinum(II,IV)-μ-bromo bis(hydrogensulfate)]

Acta Crystallographica Section C Crystal Structure Communications ◽

10.1107/s0108270192003457 ◽

1992 ◽

Vol 48 (11) ◽

pp. 1936-1939 ◽

Cited By ~ 5

Author(s):

N. Matsushita ◽

T. Taga ◽

I. Tsujikawa

Keyword(s):

Mixed Valence ◽

One Dimensional ◽

Mixed Valence Complex

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A pentaammineruthenium mixed-valence complex with 1,4-dicyanamido-2,3,5,6-tetrachlorobenzene dianion as bridging ligand: symmetry-attenuated electronic coupling between redox sites

Inorganic Chemistry ◽

10.1021/ic00344a005 ◽

1990 ◽

Vol 29 (19) ◽

pp. 3641-3644 ◽

Cited By ~ 10

Author(s):

Manuel A. S. Aquino ◽

Ann E. Bostock ◽

Robert J. Crutchley

Keyword(s):

Mixed Valence ◽

Electronic Coupling ◽

Bridging Ligand ◽

Redox Sites ◽

Mixed Valence Complex

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Heat Capacities and Phase Transitions of the Molecule-Based Mixed-Valence Complex NBu4[FeIIFeIII(ox)3] and the Mixed-Metal Complex NBu4[ZnIIFeIII(ox)3]*

Journal of the Physical Society of Japan ◽

10.1143/jpsj.69.479 ◽

2000 ◽

Vol 69 (2) ◽

pp. 479-488 ◽

Cited By ~ 24

Author(s):

Ashis Bhattacharjee ◽

Yuji Miyazaki ◽

Michio Sorai

Keyword(s):

Phase Transitions ◽

Metal Complex ◽

Mixed Valence ◽

Heat Capacities ◽

Mixed Metal ◽

Mixed Valence Complex

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ChemInform Abstract: Preparation and Characterization of (V3Cl5(tmeda)3)(V(NPh2)4) (tmeda = N,N,N′,N′-Tetramethylethylenediamine): A VII-VIII Mixed Valence Complex.

ChemInform ◽

10.1002/chin.199103280 ◽

2010 ◽

Vol 22 (3) ◽

pp. no-no

Author(s):

J. J. H. EDEMA ◽

A. MEETSMA ◽

S. GAMBAROTTA

Keyword(s):

Mixed Valence ◽

Mixed Valence Complex

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Reactivity of (C5Me5)2Sm with cyclopentadiene and cyclopentadienide: isolation of the mixed-valence complex (C5Me5)2Sm(III)(.mu.-C5H5)Sm(II)(C5Me5)2

Journal of the American Chemical Society ◽

10.1021/ja00248a025 ◽

1987 ◽

Vol 109 (14) ◽

pp. 4292-4297 ◽

Cited By ~ 61

Author(s):

William J. Evans ◽

Tamara A. Ulibarri

Keyword(s):

Mixed Valence ◽

Mixed Valence Complex

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A Single Solvating Benzene Molecule Decouples the Mixed-Valence Complex Through Intermolecular Orbital Interactions

The influence of cis/trans isomerism on the physical properties of a cyano-bridged dinuclear mixed valence complex

Design, synthesis and physico-chemical studies of a Co(II)/Co(III) mixed-valence complex: An experimental and DFT approach.

ChemInform Abstract: EXPERIMENTAL EVIDENCE FOR TRAPPED VALENCES IN THE MIXED-VALENCE COMPLEX μ-PYRAZINE-BIS(PENTAAMMINERUTHENIUM) TOSYLATE. ELECTRON PARAMAGNETIC RESONANCE, MAGNETIC SUSCEPTIBILITY, AND NUCLEAR MAGNETIC RESONANCE RESULTS

Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp*(dppe)Fe-C4-FeCp*(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)

Class III Delocalization in a Cyanide-Bridged Trimetallic Mixed-Valence Complex

Structure of a one-dimensional Br-bridged PtII-PtIV mixed-valence complex, catena-poly[bis(ethylenediamine)platinum(II,IV)-μ-bromo bis(hydrogensulfate)]

A pentaammineruthenium mixed-valence complex with 1,4-dicyanamido-2,3,5,6-tetrachlorobenzene dianion as bridging ligand: symmetry-attenuated electronic coupling between redox sites

Heat Capacities and Phase Transitions of the Molecule-Based Mixed-Valence Complex NBu4[FeIIFeIII(ox)3] and the Mixed-Metal Complex NBu4[ZnIIFeIII(ox)3]*

ChemInform Abstract: Preparation and Characterization of (V3Cl5(tmeda)3)(V(NPh2)4) (tmeda = N,N,N′,N′-Tetramethylethylenediamine): A VII-VIII Mixed Valence Complex.

Reactivity of (C5Me5)2Sm with cyclopentadiene and cyclopentadienide: isolation of the mixed-valence complex (C5Me5)2Sm(III)(.mu.-C5H5)Sm(II)(C5Me5)2

Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp(dppe)Fe-C4-FeCp(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)