Synergistic photocatalytic activity of a combination of carbon nanotubes-graphene-nickel foam nanocomposites enhanced by dielectric barrier discharge plasma technology for water purification
Abstract Degradation activity of plasma catalysis between dielectric barrier discharge (DBD) and carbon nanotubes-graphene-nickel foam (CNTs-G-Nif) has been studied in treatment of dye wastewater. CNTs-G-Nif was prepared through a two-step chemical vapor deposition (CVD) approach. The composite has been characterized by different techniques such as X-ray diffraction (XRD), scanning electron microscope (SEM) and Raman spectroscopy. SEM results showed that the Nif as the growth substrate was evenly wrapped by G and then CNTs were successfully grown on G as the support. The growth mechanism of composite was proposed. The possible coupled catalytic mechanism between DBD and CNTs-G-Nif were addressed. In addition, the modification on G-Nif was found by SEM during the discharge process in liquid phase. And the modification mechanism of DBDP acting on composites was discussed. Finally, by means of analyses of ultraviolet-visible (UV-Vis) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-mass spectrometry (LC-MS), the general degradation pathway and stepwise degradation pathways of alizarin green (AG) were proposed in detail.
