Main-Chain Ferrocene-Containing Polymers Prepared by Acyclic Diene Metathesis Polymerization: A Review

2020 ◽  
Vol 24 (9) ◽  
pp. 1010-1017 ◽  
Author(s):  
Ye Sha ◽  
Zhihua Shen ◽  
Huan Jia ◽  
Zhenyang Luo
Keyword(s):  
Main Chain ◽  
Functional Unit ◽  
Polymeric Materials ◽  
Acyclic Diene Metathesis ◽  
Polymer Backbone ◽  
Design Synthesis ◽  
Admet Polymerization ◽  
Mild Conditions ◽  
Diene Metathesis ◽  
Iron Center

Ferrocene, the crown of metallocene family, is widely studied as a functional unit in electrochemical and catalytic applications due to its sandwich structure. Ferrocene moieties can be embedded into the polymer backbone, leading to main-chain ferrocenecontaining polymers. These polymeric materials combine the unique functionalities of iron center with the processabilities of polymers. As one of the choice polymerization techniques, acyclic diene metathesis (ADMET) polymerization serves as a versatile method to prepare main-chain ferrocene-containing polymers under mild conditions using α,ω-dienes as monomers. This paper overviews main-chain ferrocene-containing polymers prepared by ADMET polymerization. Advances in the design, synthesis and applications of this class of organometallic monomers and polymers are detailed.

scholarly journals Ferrocene-Containing Conjugated Oligomers Synthesized by Acyclic Diene Metathesis Polymerization

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1334 ◽  
Author(s):  
Xin Gao ◽  
Lei Deng ◽  
Jianfeng Hu ◽  
Hao Zhang
Keyword(s):  
Electrochemical Properties ◽  
Fluorescence Intensity ◽  
Main Chain ◽  
Stokes Shift ◽  
Coupling Reaction ◽  
Conjugated Oligomers ◽  
Acyclic Diene Metathesis ◽  
Admet Polymerization ◽  
Acyclic Diene Metathesis Polymerization ◽  
Diene Metathesis

A series of conjugated, symmetrical, and ferrocene-containing main-chain monomers was prepared following a gentle coupling reaction. Ferrocene-containing oligomers with all-trans-configured vinylene bonds could be synthesized via acyclic diene metathesis (ADMET) polymerization. These oligomers had a larger Stokes shift (2400 to 2600 cm−1) and both exhibited stable and reversible electrochemistry. Meanwhile, the copolymerization of 1,1’-bis[1-methyl-2-(4-vinylphenyl)ethenyl]ferrocene with 2,7-divinyl-9,9-dioctylfluorene was achieved. The structurally regular copolymers proved their optical and electrochemical properties. The fluorescence intensity of the copolymer gradually enhanced with the increasing number of fluorene units. At the same time, it was also found that the color of the copolymers had a significant change from yellow-green to red.

Functional α,ω-dienes via thiol-Michael chemistry: synthesis, oxidative protection, acyclic diene metathesis (ADMET) polymerization and radical thiol–ene modification

2014 ◽  
Vol 5 (21) ◽  
pp. 6225-6235 ◽  
Author(s):  
Johannes A. van Hensbergen ◽  
Taylor W. Gaines ◽  
Kenneth B. Wagener ◽  
Robert P. Burford ◽  
Andrew B. Lowe
Keyword(s):  
The Novel ◽  
Acyclic Diene Metathesis ◽  
Admet Polymerization ◽  
Oxidative Protection ◽  
Diene Metathesis

The synthesis of the novel α,ω-diene 2-(undec-10-en-1-yl)tridec-12-en-1-yl acrylate is described.

Acyclic diene metathesis (ADMET) polymerization

1991 ◽  
Vol 24 (10) ◽  
pp. 2649-2657 ◽  
Author(s):  
K. B. Wagener ◽  
J. M. Boncella ◽  
J. G. Nel
Keyword(s):  
Acyclic Diene Metathesis ◽  
Admet Polymerization ◽  
Diene Metathesis

Acyclic diene metathesis (ADMET) polymerization of allyl undec-10-enoate and some related esters

2006 ◽  
Vol 691 (24-25) ◽  
pp. 5431-5437 ◽  
Author(s):  
Andrew J. Hall ◽  
Philip Hodge ◽  
Stephen D. Kamau ◽  
Abderrakak Ben-Haida
Keyword(s):  
Acyclic Diene Metathesis ◽  
Admet Polymerization ◽  
Diene Metathesis
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