Influence of the Preparation Method on Catalytic Properties of Pd/TiO2 Catalysts in the Reaction of Partial Oxidation of Methanol

2013 ◽  
Vol 2 (1) ◽  
pp. 27-34 ◽  
Author(s):  
R. Wojcieszak ◽  
R. Mateos-Blanco ◽  
D. Hauwaert ◽  
S. R.G. Carrazan ◽  
E. M. Gaigneaux ◽  
...  
Keyword(s):  
Partial Oxidation ◽  
Preparation Method ◽  
Catalytic Properties ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol

scholarly journals Effect of Mo Dispersion on the Catalytic Properties and Stability of Mo–Fe Catalysts for the Partial Oxidation of Methanol

Molecules ◽  
2020 ◽  
Vol 25 (10) ◽  
pp. 2410
Author(s):  
Shuai Zhang ◽  
Minghan Han
Keyword(s):  
Surface Layer ◽  
Surface Area ◽  
Partial Oxidation ◽  
Active Sites ◽  
Oxygen Vacancies ◽  
Catalyst Surface ◽  
Catalytic Properties ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol ◽  
Fe Catalysts

Mo–Fe catalysts with different Mo dispersions were synthesized with fast (Cat-FS, 600 r·min−1) or slow stirring speed (Cat-SS, 30 r·min−1) by the coprecipitation method. Improving the stirring speed strengthened the mixing of the solution and increased the dispersion of particles in the catalyst, which exhibited favorable activity and selectivity. The byproduct (dimethyl ether (DME)) selectivity increased from 2.3% to 2.8% with Cat-SS, while it remained unchanged with Cat-FS in a stability test. The aggregation of particles and thin Mo-enriched surface layer decreased the catalyst surface area and slowed down the reoxidation of reduced active sites with Cat-SS, leaving more oxygen vacancies which promoted the formation of DME by the nonoxidative channel.

Modulation of the selectivity in partial oxidation of methanol over CuZnAl catalysts by adding CO 2 and/or H 2 into the reaction feed

2015 ◽  
Vol 168-169 ◽  
pp. 14-24 ◽  
Author(s):  
Silvia R. González Carrazán ◽  
Robert Wojcieszak ◽  
Raquel. M. Blanco ◽  
Cecilia Mateos-Pedrero ◽  
Patricio Ruiz
Keyword(s):  
Partial Oxidation ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol

scholarly journals Partial Oxidation of Methanol Over Highly Dispersed Vanadia Supported on Silica SBA-15

2005 ◽  
Vol 105 (1-2) ◽  
pp. 1-8 ◽  
Author(s):  
C. Hess ◽  
Ian J. Drake ◽  
James D. Hoefelmeyer ◽  
T. Don Tilley ◽  
Alex T. Bell
Keyword(s):  
Partial Oxidation ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol ◽  
Highly Dispersed

Partial oxidation of methanol to produce hydrogen over CuZn-based catalysts

1997 ◽  
Vol 162 (1-2) ◽  
pp. 281-297 ◽  
Author(s):  
L. Alejo ◽  
R. Lago ◽  
M.A. Peña ◽  
J.L.G. Fierro
Keyword(s):  
Partial Oxidation ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol
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