Nonlinear Optical Properties of Materials Based on Graphene Oxide: A Review

2019 ◽  
Vol 4 (3) ◽  
pp. 151-159
Author(s):  
Mojtaba Ebrahimi ◽  
Abdolnasser Zakery

Background: Nonlinear optical properties of Graphene and Graphene Oxide have been widely used in industry and academia. Graphene oxide disperses easily in water and has easier interaction with other materials because of the presence of oxygen groups. So, this feature of Graphene oxide enables us to manipulate its nonlinear optical properties by combining it with other nanoparticles. Objective: We introduced recent advances in the nonlinear optical properties of materials based on Graphene oxide. Methods: Nonlinear optical properties and optical limiting of Graphene oxide and/or its composites with various nanoparticles, considering the wavelength and the incident pulse width, are investigated in this review. Conclusion: At low intensities and in all pulse regimes, saturation absorption seems to be the dominant mechanism of nonlinear absorption in Graphene oxide, while at higher intensities, the main mechanism is the reverse saturation absorption. In the regime of very short pulses of picoseconds and femtoseconds, the dominant mechanisms of two-photon and multiphoton absorption lead to reverse saturation. In the nanosecond pulse regime, long laser pulses and short pulses with high pulse repetition rates, excited-state absorption and nonlinear scattering due to thermal effects are causing the nonlinear process.

PLoS ONE ◽  
2021 ◽  
Vol 16 (9) ◽  
pp. e0257808
Author(s):  
Dian Alwani Zainuri ◽  
Mundzir Abdullah ◽  
Muhamad Fikri Zaini ◽  
Hazri Bakhtiar ◽  
Suhana Arshad ◽  
...  

The Ultraviolet-visible (UV-Vis) spectra indicate that anthracenyl chalcones (ACs) have high maximum wavelengths and good transparency windows for optical applications and are suitable for optoelectronic applications owing to their HOMO–LUMO energy gaps (2.93 and 2.76 eV). Different donor substituents on the AC affect their dipole moments and nonlinear optical (NLO) responses. The positive, negative, and neutral electrostatic potential regions of the molecules were identified using molecular electrostatic potential (MEP). The stability of the molecule on account of hyperconjugative interactions and accompanying charge delocalization was analyzed using natural bond orbital (NBO) analysis. Open and closed aperture Z-scans were performed using a continuous-wave frequency-doubled diode-pumped solid-state (DPSS) laser to measure the nonlinear absorption and nonlinear refractive index coefficients, respectively. The valley-to-peak profile of AC indicated a negative nonlinear refractive index coefficient. The obtained single crystals possess reverse saturation absorption due to excited-state absorption. The structural and nonlinear optical properties of the molecules have been discussed, along with the role of anthracene substitution for enhancing the nonlinear optical properties. The calculated third-order susceptibility value was 1.10 x10-4 esu at an intensity of 4.1 kW/cm2, higher than the reported values for related chalcone derivatives. The NLO response for both ACs offers excellent potential in optical switching and limiting applications.


2016 ◽  
Vol 15 (7) ◽  
pp. 910-919 ◽  
Author(s):  
Zongle Li ◽  
Chunying He ◽  
Zhao Wang ◽  
Yachen Gao ◽  
Yongli Dong ◽  
...  

An investigation of the enhanced optical nonlinearity of ethylenediamine-modified graphene oxide covalently functionalized with a tetracarboxylic Zn(ii) phthalocyanine.


2012 ◽  
Vol 116 (49) ◽  
pp. 25955-25961 ◽  
Author(s):  
Panit Chantharasupawong ◽  
Reji Philip ◽  
Narayanan T. Narayanan ◽  
Parambath M. Sudeep ◽  
Akshay Mathkar ◽  
...  

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