scholarly journals Внутридоплеровские резонансы, обусловленные фотоионизацией атомов в тонких газовых ячейках

2022 ◽  
Vol 130 (3) ◽  
pp. 353
Author(s):  
А.Ч. Измайлов

By analogy with the well-tested method of high-resolution spectroscopy in thin gas cells for the processes of optical pumping of atoms, this work shows the possibility of detecting narrow sub-Doppler optical resonances caused directly by straight photoionization of atoms (or molecules) in such cells. The structure of the established nontrivial resonances substantially depends on the probability of photoionization of atoms and dimensions of such a cell, the internal thickness of which is many times smaller than its diameter. Of particular interest is the broadening of the considered sub-Doppler resonances, which is determined directly by the photoionization cross section of atoms and the intensity of radiation causing ionization. Under certain conditions, such photoionization broadening can be measured experimentally with high accuracy, as a result of which it is possible to obtain new important information about ionization processes in atoms and molecules.

Atoms ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 27
Author(s):  
Jean-Paul Mosnier ◽  
Eugene T. Kennedy ◽  
Jean-Marc Bizau ◽  
Denis Cubaynes ◽  
Ségolène Guilbaud ◽  
...  

High-resolution K-shell photoionization cross-sections for the C-like atomic nitrogen ion (N+) are reported in the 398 eV (31.15 Å) to 450 eV (27.55 Å) energy (wavelength) range. The results were obtained from absolute ion-yield measurements using the SOLEIL synchrotron radiation facility for spectral bandpasses of 65 meV or 250 meV. In the photon energy region 398–403 eV, 1s⟶2p autoionizing resonance states dominated the cross section spectrum. Analyses of the experimental profiles yielded resonance strengths and Auger widths. In the 415–440 eV photon region 1s⟶(1s2s22p2 4P)np and 1s⟶(1s2s22p2 2P)np resonances forming well-developed Rydberg series up n=7 and n=8 , respectively, were identified in both the single and double ionization spectra. Theoretical photoionization cross-section calculations, performed using the R-matrix plus pseudo-states (RMPS) method and the multiconfiguration Dirac-Fock (MCDF) approach were bench marked against these high-resolution experimental results. Comparison of the state-of-the-art theoretical work with the experimental studies allowed the identification of new resonance features. Resonance strengths, energies and Auger widths (where available) are compared quantitatively with the theoretical values. Contributions from excited metastable states of the N+ ions were carefully considered throughout.


2010 ◽  
Vol 81 (6) ◽  
pp. 063106 ◽  
Author(s):  
Luis Velarde ◽  
Daniel P. Engelhart ◽  
Daniel Matsiev ◽  
Jerry LaRue ◽  
Daniel J. Auerbach ◽  
...  

2011 ◽  
Vol 84 (1) ◽  
Author(s):  
D. A. Esteves ◽  
R. C. Bilodeau ◽  
N. C. Sterling ◽  
R. A. Phaneuf ◽  
A. L. D. Kilcoyne ◽  
...  

Author(s):  
Charles A Bowesman ◽  
Meiyin Shuai ◽  
Sergei N Yurchenko ◽  
Jonathan Tennyson

Abstract Indications of aluminium monoxide in atmospheres of exoplanets are being reported. Studies using high resolution spectroscopy should allow a strong detection but require high accuracy laboratory data. A Marvel (measured active rotational-vibrational energy levels) analysis is performed for the available spectroscopic data on 27Al16O: 22 473 validated transitions are used to determine 6 485 distinct energy levels. These empirical energy levels are used to provide an improved, spectroscopically accurate version of the ExoMol ATP line list for 27Al16O; at the same time the accuracy of the line lists for the isotopically-substituted species 26Al16O, 27Al17O and 27Al18O are improved by correcting levels in line with the corrections used for 27Al16O. These line lists are available from the ExoMol database at http://www.exomol.com.


1984 ◽  
Vol 40 (1) ◽  
pp. 120-122
Author(s):  
L. A. Budkin ◽  
O. G. Okhotnikov ◽  
G. T. Pak ◽  
A. I. Pikhtelev ◽  
S. L. Puzanov

Author(s):  
Jean-Paul Mosnier ◽  
Eugene T Kennedy ◽  
Jean-Marc Bizau ◽  
Denis Cubaynes ◽  
Ségolène Guilbaud ◽  
...  

High-resolution K-shell photoionization cross-sections for the C-like atomic nitrogen ion (N+) are reported in the 398 eV (31.15 Å) to 450 eV (27.55 Å) energy (wavelength) range. The results were obtained from absolute ion-yield measurements using the SOLEIL synchrotron radiation facility for spectral bandpasses of 65 meV or 250 meV. In the photon energy region 398 eV - 403 eV, 1s⟶2p autoionizing resonance states dominated the cross section spectrum. Analyses of the experimental profiles yielded resonance strengths and Auger widths. In the 415 eV - 440 eV photon region 1s⟶1s2s22p2 4Pnp and 1s⟶1s2s22p2 2Pnp resonances forming well-developed Rydberg series up n=7 and n=8 , respectively, were identified in both the single and double ionization spectra. Theoretical photoionization cross-section calculations, performed using the R-matrix plus pseudo-states (RMPS) method and the multiconfiguration Dirac-Fock (MCDF) approach were bench marked against these high-resolution experimental results. Comparison of the state-of-the-art theoretical work with the experimental studies allowed the identification of new resonance features. Resonance strengths, energies and Auger widths (where available) are compared quantitatively with the theoretical values. Contributions from excited metastable states of the N+ ions were carefully considered throughout.


1988 ◽  
Vol 102 ◽  
pp. 71-73
Author(s):  
E. Jannitti ◽  
P. Nicolosi ◽  
G. Tondello

AbstractThe photoabsorption spectra of the carbon ions have been obtained by using two laser-produced plasmas. The photoionization cross-section of the CV has been absolutely measured and the value at threshold, σ=(4.7±0.5) × 10−19cm2, as well as its behaviour at higher energies agrees quite well with the theoretical calculations.


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