Synthesis, Characterization and Catalytic Potency of Zn-based MOF for Knoevenagel Condensation Reaction

Abstract: A Zn based metal organic framework with pyridine 2, 5-dicarboxylate (Zn-based MOF) were prepared as a reusable heterogeneous catalyst using solvothermal method. Zn-based MOF was used as heterogeneous catalyst for synthesis 5-arylidene malononitrile in ethanol under reflux condition. The attractive features of present method are mild reaction condition, short reaction time, simplicity, easy separation of catalyst and excellent yield. Keywords: Metal organic framework, heterogeneous catalyst, solvothermal method.

Download Full-text

A mononuclear Cu(II)-based metal-organic framework as an efficient heterogeneous catalyst for chemical transformation of CO2 and Knoevenagel condensation reaction

Inorganic Chemistry Communications ◽

10.1016/j.inoche.2019.01.022 ◽

2019 ◽

Vol 101 ◽

pp. 87-92 ◽

Cited By ~ 12

Author(s):

Feng Guo

Keyword(s):

Heterogeneous Catalyst ◽

Chemical Transformation ◽

Knoevenagel Condensation ◽

Condensation Reaction ◽

Metal Organic Framework ◽

Metal Organic ◽

Knoevenagel Condensation Reaction ◽

Efficient Heterogeneous Catalyst ◽

Organic Framework

Download Full-text

A new imidazole-functionalized 3D-cobalt metal-organic framework as a high efficiency heterogeneous catalyst for Knoevenagel condensation reaction of furfural

Journal of Molecular Structure ◽

10.1016/j.molstruc.2020.128744 ◽

2020 ◽

Vol 1221 ◽

pp. 128744

Author(s):

Zhida Liu ◽

Liangmin Ning ◽

Kaiyuan Wang ◽

Lixi Feng ◽

Wen Gu ◽

...

Keyword(s):

Heterogeneous Catalyst ◽

High Efficiency ◽

Knoevenagel Condensation ◽

Condensation Reaction ◽

Metal Organic Framework ◽

Cobalt Metal ◽

Metal Organic ◽

Knoevenagel Condensation Reaction ◽

Organic Framework

Download Full-text

A highly stable 3D metal−organic framework for selectively luminescent sensing and knoevenagel condensation reaction

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2019.05.036 ◽

2019 ◽

Vol 277 ◽

pp. 25-31 ◽

Cited By ~ 6

Author(s):

Feng Guo ◽

Changhua Su ◽

Zepeng Chu ◽

Minghui Zhao

Keyword(s):

Knoevenagel Condensation ◽

Condensation Reaction ◽

Metal Organic Framework ◽

Metal Organic ◽

Knoevenagel Condensation Reaction ◽

Luminescent Sensing ◽

Organic Framework

Download Full-text

A Zinc(II) Porous Metal-Organic Framework and Its Morphologically Controlled Catalytic Properties in the Knoevenagel Condensation Reaction

ChemPlusChem ◽

10.1002/cplu.201700327 ◽

2017 ◽

Vol 82 (9) ◽

pp. 1182-1187 ◽

Cited By ~ 7

Author(s):

Jiajia Wang ◽

Xiaoxiao Wang ◽

Haitao Xu ◽

Xi Zhao ◽

Zhizhong Zheng ◽

...

Keyword(s):

Catalytic Properties ◽

Knoevenagel Condensation ◽

Condensation Reaction ◽

Metal Organic Framework ◽

Porous Metal ◽

Metal Organic ◽

Knoevenagel Condensation Reaction ◽

Organic Framework

Download Full-text

Bifunctional design of stable metal-organic framework bearing triazole–carboxylate mixed ligand: Highly efficient heterogeneous catalyst for knoevenagel condensation reaction under mild conditions

Catalysis Communications ◽

10.1016/j.catcom.2020.106032 ◽

2020 ◽

Vol 142 ◽

pp. 106032

Author(s):

Feixiong Liu ◽

Sandeep Kumar ◽

Shuangshuang Li ◽

Hengzhi You ◽

Peng Ren ◽

...

Keyword(s):

Heterogeneous Catalyst ◽

Knoevenagel Condensation ◽

Condensation Reaction ◽

Metal Organic Framework ◽

Mixed Ligand ◽

Mild Conditions ◽

Highly Efficient ◽

Metal Organic ◽

Knoevenagel Condensation Reaction ◽

Efficient Heterogeneous Catalyst

Download Full-text

CaO nanoparticles incorporated metal organic framework (NH2-MIL-101) for Knoevenagel condensation reaction

Arabian Journal of Chemistry ◽

10.1016/j.arabjc.2021.103588 ◽

2021 ◽

pp. 103588

Author(s):

Huda I. Aljaddua ◽

Mosaed S. Alhumaimess ◽

Hassan M.A. Hassan

Keyword(s):

Knoevenagel Condensation ◽

Condensation Reaction ◽

Metal Organic Framework ◽

Metal Organic ◽

Knoevenagel Condensation Reaction ◽

Organic Framework

Download Full-text

The synthesis of a bifunctional copper metal organic framework and its application in the aerobic oxidation/Knoevenagel condensation sequential reaction

Dalton Transactions ◽

10.1039/c6dt01690a ◽

2016 ◽

Vol 45 (35) ◽

pp. 13917-13924 ◽

Cited By ~ 44

Author(s):

Zongcheng Miao ◽

Yi Luan ◽

Chao Qi ◽

Daniele Ramella

Keyword(s):

Knoevenagel Condensation ◽

Condensation Reaction ◽

Metal Organic Framework ◽

Aerobic Oxidation ◽

Reaction System ◽

One Pot ◽

Sequential Reaction ◽

Metal Organic ◽

Knoevenagel Condensation Reaction ◽

Organic Framework

A novel one-pot aerobic oxidation/Knoevenagel condensation reaction system is developed employing a Cu(ii)/basic bifunctional metal–organic framework (MOF) as the catalyst.

Download Full-text

Synthesis and application of core–shell magnetic metal–organic framework composites Fe3O4/IRMOF-3

RSC Advances ◽

10.1039/c6ra17824c ◽

2016 ◽

Vol 6 (96) ◽

pp. 94113-94118 ◽

Cited By ~ 9

Author(s):

Weigang Li ◽

Gang Li ◽

Dan Liu

Keyword(s):

Knoevenagel Condensation ◽

Condensation Reaction ◽

Metal Organic Framework ◽

Core Shell ◽

Magnetic Metal ◽

Metal Organic ◽

Knoevenagel Condensation Reaction ◽

Novel Method ◽

Organic Framework

A core–shell structured magnetic MOF composite, Fe3O4/IRMOF-3, was synthesized by a novel method and applied as a catalyst in the Knoevenagel condensation reaction.

Download Full-text