scholarly journals Recent Developments of Organotransition-metal Catalysts for Polymerization: 1. The Synthesis of Olefin Elastomers

2004 ◽  
Vol 77 (9) ◽  
pp. 312-316
Author(s):  
Shojiro KAITA ◽  
Yasuo WAKATSUKI
Keyword(s):  
Metal Catalysts ◽  
Recent Developments

Recent developments in the chemistry of low-coordinated organophosphorus compounds

2005 ◽  
Vol 77 (12) ◽  
pp. 2011-2020 ◽  
Author(s):  
Masaaki Yoshifuji
Keyword(s):  
Transition Metal ◽  
Coordination Number ◽  
Organophosphorus Compounds ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Coupling Reactions ◽  
Recent Developments

Sterically protected organophosphorus compounds are described, involving diphosphenes, phosphaethenes, diphosphinidenecyclobutenes (DPCBs), phosphaalkynes, phosphaquinones, diphosphathienoquinones, and so on of coordination number 2 or 1. Application of the DPCBs as well as phosphinophosphaethenes as a ligand of transition-metal catalysts for several organic coupling reactions has been investigated.

scholarly journals Direct Transamidation Reactions: Mechanism and Recent Advances

Molecules ◽  
2018 ◽  
Vol 23 (9) ◽  
pp. 2382 ◽  
Author(s):  
Paola Acosta-Guzmán ◽  
Alejandra Mateus-Gómez ◽  
Diego Gamba-Sánchez
Keyword(s):  
Carboxylic Acid ◽  
Chemical Industry ◽  
Metal Catalysts ◽  
Direct Reaction ◽  
Valuable Alternative ◽  
Recent Advances ◽  
Other Substances ◽  
Recent Developments ◽  
Nitrogen Nucleophiles ◽  
Reactions Mechanism

Amides are undeniably some of the most important compounds in Nature and the chemical industry, being present in biomolecules, materials, pharmaceuticals and many other substances. Unfortunately, the traditional synthesis of amides suffers from some important drawbacks, principally the use of stoichiometric activators or the need to use highly reactive carboxylic acid derivatives. In recent years, the transamidation reaction has emerged as a valuable alternative to prepare amides. The reactivity of amides makes their direct reaction with nitrogen nucleophiles difficult; thus, the direct transamidation reaction needs a catalyst in order to activate the amide moiety and to promote the completion of the reaction because equilibrium is established. In this review, we present research on direct transamidation reactions ranging from studies of the mechanism to the recent developments of more applicable and versatile methodologies, emphasizing those reactions involving activation with metal catalysts.

Recent Developments on the Synthesis of Biologically Significant bis/tris(indolyl)methanes under Various Reaction Conditions: A Review

2020 ◽  
Vol 24 (6) ◽  
pp. 583-621
Author(s):  
Arvind Singh ◽  
Gurpreet Kaur ◽  
Bubun Banerjee
Keyword(s):  
Ionic Liquids ◽  
Bioactive Compounds ◽  
Building Block ◽  
Heterogeneous Catalysts ◽  
Metal Catalysts ◽  
Reaction Conditions ◽  
Naturally Occurring ◽  
Wide Range ◽  
Anti Cancer ◽  
Recent Developments

Bis(indolyl)methane skeleton is the main building block of many naturally occurring bioactive compounds. Bis(indolyl)methanes are found to possess a wide range of pharmaceuitical efficacies. These important scaffolds are being used as anti-cancer, antioxidant, anti-bacterial, anti-inflammatory, and anti-proliferative agents. In this review, we summarized the latest developments on the synthesis of various bis/tris(indolyl)methane derivatives from the reactions of two equivalents of indoles and one equivalent of aldehydes or indole-3-carbaldehydes under various reaction conditions. More than hundred different catalysts were employed for these transformations which include various metal catalysts, ionic liquids, organocatalysts, surfactants, homogeneous, heterogeneous catalysts etc.

scholarly journals The Use of Domino Reactions for the Synthesis of Chiral Rings

Synthesis ◽  
2020 ◽  
Vol 52 (24) ◽  
pp. 3837-3854
Author(s):  
Hélène Pellissier
Keyword(s):  
Nitrogen Atom ◽  
Sulfur Atom ◽  
Short Review ◽  
Metal Catalysts ◽  
Domino Reactions ◽  
Carbon Ring ◽  
Chiral Rings ◽  
Recent Developments

This short review highlights the recent developments reported in the last four years on the asymmetric construction of chiral rings based on enantioselective domino reactions promoted by chiral metal catalysts.1 Introduction2 Formation of One Ring Containing One Nitrogen Atom3 Formation of One Ring Containing One Oxygen/Sulfur Atom4 Formation of One Ring Containing Several Heterocyclic Atoms5 Formation of One Carbon Ring6 Formation of Two Rings7 Conclusion

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