scholarly journals Two-Dimensional Mathematical Model for Carbon Monoxide Oxidation Process on the Platinum Catalyst Surface

2018 ◽  
Vol 12 (4) ◽  
pp. 451-455 ◽  
Author(s):  
Petro Kostrobii ◽  
◽  
Iryna Ryzha ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 116-124
Author(s):  
P. P. Kostrobij ◽  
◽  
I. A. Ryzha ◽  

The stability conditions for mathematical models of carbon monoxide oxidation on the surface of gold nanoparticles are investigated. The cases of reaction mechanisms of one-step and step-by-step transformation of reagents are consecutively considered. Using the stability analysis by Lyapunov method, it is shown that models which take into account the possibility of structural changes of the catalyst surface can predict the occurrence of oscillatory mode in the system as a result of Hopf instability.


Author(s):  
Petro Kostrobij ◽  
Iryna Ryzha

In the paper a study of a two-dimensional mathematical model of carbon monoxide oxidation on the Pt catalyst surface according to the Langmuir-Hinshelwood mechanism is presented. This model takes into account the nanoinhomogeneities of Pt(110) surface and diffusion processes of CO molecules and oxygen atoms adsorbed on the catalyst surface. It is shown that the structural changes of Pt(110) surface significantly affect the character of oscillatory mode of reaction, whereas the adsorbed oxygen atoms can be considered immobile.


1982 ◽  
Vol 120 (2) ◽  
pp. L453-L460 ◽  
Author(s):  
M.G. Goodman ◽  
M.B. Cutlip ◽  
C.N. Kenney ◽  
W. Morton ◽  
D. Mukesh

Author(s):  
H.D. Cochran ◽  
R.G. Donnelly ◽  
M. Modell ◽  
R.F. Baddour

1982 ◽  
Vol 120 (2) ◽  
pp. L453-L460
Author(s):  
M.G. Goodman ◽  
M.B. Cutlip ◽  
C.N. Kenney ◽  
W. Morton ◽  
D. Mukesh

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