Stability of carbon monoxide oxidation process on gold nanoparticles

2020 ◽  
Vol 8 (1) ◽  
pp. 116-124
Author(s):  
P. P. Kostrobij ◽  
◽  
I. A. Ryzha ◽  
Keyword(s):  
Carbon Monoxide ◽  
Gold Nanoparticles ◽  
Reaction Mechanisms ◽  
Structural Changes ◽  
Oxidation Process ◽  
Lyapunov Method ◽  
Catalyst Surface ◽  
Carbon Monoxide Oxidation ◽  
One Step ◽  
The Stability

The stability conditions for mathematical models of carbon monoxide oxidation on the surface of gold nanoparticles are investigated. The cases of reaction mechanisms of one-step and step-by-step transformation of reagents are consecutively considered. Using the stability analysis by Lyapunov method, it is shown that models which take into account the possibility of structural changes of the catalyst surface can predict the occurrence of oscillatory mode in the system as a result of Hopf instability.

Deposition of gold nanoparticles on organo-kaolinite — Application in electrocatalysis for carbon monoxide oxidation

2011 ◽  
Vol 89 (7) ◽  
pp. 845-853 ◽  
Author(s):  
Sadok Letaief ◽  
Wendy Pell ◽  
Christian Detellier
Keyword(s):  
Carbon Monoxide ◽  
Gold Nanoparticles ◽  
Photoelectron Spectroscopy ◽  
Fine Particles ◽  
Raw Materials ◽  
Carbon Monoxide Oxidation ◽  
Functional Materials ◽  
Metallic State ◽  
Oxidation Reactions ◽  
X Ray

The clay mineral kaolinite was used as support of gold nanoparticles for heterogeneous catalysis of oxidation reactions, particularly of carbon monoxide oxidation. The application of clay minerals in the preparation of new functional materials provides an alternative approach for the use of these abundant raw materials. To improve the physicochemical properties of kaolinite, as well as to ensure a strong immobilization of the adsorbed species, kaolinite was functionalized by grafting 2-amino-2-methyl-1,3-propanediol on the internal and external surfaces of the octahedral sheets by reaction with the aluminol groups. Gold nanoparticles were then deposited on the external surfaces of the fine particles of the functionalized kaolinite. The resulting gold kaolinite nanohybrid material was characterized by various physicochemical techniques. X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and energy-dispersive X-ray spectrometry confirmed that gold was effectively reduced to the metallic state during adsorption onto the external surfaces of the modified kaolinite. The gold nanoparticles have a narrow size distribution: more than 88% are less than 4 nm in diameter. Gold nanoparticles deposited on kaolinite catalyze the electro-oxidation of carbon monoxide in alkaline solution at room temperature.

Carbon monoxide oxidation on lithium fluoride supported gold nanoparticles: A significance of F-centers

2015 ◽  
Vol 213-214 ◽  
pp. 42-45 ◽  
Author(s):  
I.V. Tvauri ◽  
B.E. Gergieva ◽  
V.D. Magkoeva ◽  
G.S. Grigorkina ◽  
A.P. Bliev ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Gold Nanoparticles ◽  
Lithium Fluoride ◽  
Carbon Monoxide Oxidation ◽  
Supported Gold Nanoparticles ◽  
Supported Gold ◽  
F Centers

Gold Nanoparticles Supported on Carbon Nitride: Influence of Surface Hydroxyls on Low Temperature Carbon Monoxide Oxidation

ACS Catalysis ◽  
2012 ◽  
Vol 2 (6) ◽  
pp. 1138-1146 ◽  
Author(s):  
Joseph A. Singh ◽  
Steven H. Overbury ◽  
Nancy J. Dudney ◽  
Meijun Li ◽  
Gabriel M. Veith
Keyword(s):  
Carbon Monoxide ◽  
Gold Nanoparticles ◽  
Low Temperature ◽  
Carbon Nitride ◽  
Carbon Monoxide Oxidation ◽  
Surface Hydroxyls

The stability and oscillations of carbon monoxide oxidation over platinum supported catalyst. Effect of butene

1982 ◽  
Vol 37 (12) ◽  
pp. 1807-1810 ◽  
Author(s):  
D. Mukesh ◽  
M.C. Cutlip ◽  
M. Goodman ◽  
C.N. Kenney ◽  
W. Morton
Keyword(s):  
Carbon Monoxide ◽  
Supported Catalyst ◽  
Carbon Monoxide Oxidation ◽  
The Stability ◽  
Catalyst Effect
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